Abstract
Samples and fractions of a membrane-forming polymer poly[1-(-trimethylgermyl)propyne], with the molecular weight within 4 < M × 10- 4 < 170 were studied in cyclohexane by methods of molecular hydrodynamics (centrifugal sedimentation, translational isothermal diffusion, and viscometry). The molecular weight dependences of the hydrodynamic characteristics were determined and analyzed. These dependences were used to estimate the equilibrium rigidities of the poly[1-(trimethylgermyl)propyne] chains. The size of the macromolecules was studied as influenced by the bulk effects. The results obtained are compared with published data for poly[1-(trimethylsilyl)propyne].
Similar content being viewed by others
REFERENCES
Plate, N.A., Antipov, E.M., Teplyakov, V.V. et al., Vysokomol. Soedin., Ser. A, 1990, vol. 32, no. 6, pp. 1123-1138.
Litvinova, E.G. and Khotimsky, V.S., Abstracts of Papers, Second Int. Symp. [Progress in Membrane Science and Technology,] Enschede (Netherlands), June 273July 1, 1994, p. 57.
Masuda, H. and Higashimura, T., Adv. Polym. Sci., 1987, vol. 81, pp. 121-159.
Masuda, H., Isobe, E., Higashimura, T., and Takada, K., J. Am. Chem. Soc., 1983, vol. 105, no. 25, pp. 7473-7477.
Plate, N.A., Bokarev, A.K., Kaliuzhnyi, N.E., et al., J. Membr. Sci., 1991, vol. 60, no. 1, pp. 13-19.
Takada, K., Matsuya, H., Masuda, H., and Higashimura, T., J. Appl. Polym. Sci., 1985, vol. 30, no. 4, pp. 1605-1616.
Savoca, A., Surnamer, A., and Tieu, Ch., Macromolecules, 1993, vol. 26, no. 23, pp. 6211-6216.
Shtennikova, I.N., Kolbina, G.F., Korneeva, E.V., et al., Zh. Prikl. Khim., 1998, vol. 71, no. 8, pp. 1350-1355.
Ryumtsev, E.I., Evlampieva, N.P., Shtennikova, I.N., et al., Vysokomol. Soedin., Ser. A, 1999, vol. 41, no. 7, pp. 1169-1175.
Shtennikova, I.N., Kolbina, G.F., Yakimansky, A., et al., Eur. Polym. J., 1999, vol. 35, no. 12, pp. 2073-2078.
Khotimskii, V.S., Chirkova, M.V., Litvinova, E.G., et al., Vysokomol. Soedin., Ser. A, 2000, vol. 42, no. 7, pp. 1169-1175.
Tsvetkov, V.N., Eskin, V.E., and Frenkel', S.Ya., Struktura makromolekul v rastvorakh (Structure of Macromolecules in Solutions), Moscow: Nauka, 1964.
Tsvetkov, V.N., Zhestkotsepnye polimery (Rigid-Chain Polymers), Leningrad: Nauka, 1986.
Pavlov, G.M. and Frenkel', S.Ya., Vysokomol. Soedin., Ser. B, 1986, vol. 20, no. 5, pp. 353-357.
Pavlov, G.M. and Frenkel', S.Ya., Prog. Coll. Polym. Sci., 1995, vol. 99, pp. 101-108.
Budtov, V.P., Fizicheskaya khimiya rastvorov polimerov (Physical Chemistry of Polymer Solutions). St. Petersburg: Khimiya, 1992.
Pavlov, G.M. and Frenlel', S.Ya., Vysokomol. Soedin., Ser. B, 1982. vol. 24, no. 3, pp. 178-180.
Pavlov, G.M., Rowe, A.J., and Harding, S.E., Trends Anal. Chem., 1997, vol. 16, no. 7, pp. 401-405.
Pavlov, G.M., Harding, S.E., and Rowe, A.J., Prog. Coll. Polym. Sci., 1999, vol. 113, pp. 76-80.
Pavlov, G.M., Korneeva, E.V., Zhumel', K., et al., Zh. Prikl. Khim., 2000, vol. 73, no. 6, pp. 992-996.
Pavlov, G.M., Korneeva, E.V., Mikhailova, N.A., and Anan'eva, E.P., Biofizika, 1992, vol. 37, no. 6, pp. 1038-1043.
Pavlov, G.M., Korneeva, E.V., Mikhailova, N.A., et al., Vysokomol. Soedin., Ser. A, 1993, vol. 35, no. 10, pp. 1647-1651.
Shtennikova, I.N., Kolbina, G.F., Khotimskii, V.S., et al., Vysokomol. Soedin., Ser. A, 1998, vol. 40, no. 10, pp. 1569-1576.
Ptitsyn, O.B. and Eizner, Yu.E., Zh. Tekh. Fiz., 1959, vol. 29, no. 9, pp. 1105-1111.
Bushin, S.V. and Astapenko, E.P., Vysokoml. Soedin., Ser. A, 1986, vol. 28, no. 7, pp. 1499-1503.
Pavlov, G.M., Panarin, E.F., Korneeva, E.V., et al., Vysokomol. Soedin., Ser. A, 1990, vol. 32, no. 6, pp. 1190-1196.
Gray, H.B., Bloomfield, V.A., and Hearst, J.E., J. Chem. Phys., 1967, vol. 46, no. 4, pp. 1493-1498.
Hearst, J.E. and Stockmayer, W., J. Chem. Phys., 1962, vol. 37, no. 7, pp. 1425-1432.
Yamakawa, H. and Fujii, M., Macromolecules, 1974, vol. 7, no. 1, pp. 128-134.
Tsetkov, V.N., Lavrenko, P.N., Pavlov, G.M., et al., Vysokomol. Soedin., Ser. A., 1982, vol. 24, no. 11, pp. 2343-2351.
Pavlov, G.M., Selyunin. S.G., Shil'dyaeva, N.A., et al., Vysokomol. Soedin., Ser. A, 1985, vol. 27, no. 8, pp. 1627-1632.
Masuda, H., Isobe, E., and Higashimura, T., Macromolecules, 1985, vol. 18, no. 5, pp. 841-847.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pavlov, G.M., Evlampieva, N.P., Mikhailova, N.A. et al. Hydrodynamic and Molecular Characteristics of Poly[1-(trimethylgermyl)propyne] . Russian Journal of Applied Chemistry 74, 286–291 (2001). https://doi.org/10.1023/A:1012742721922
Issue Date:
DOI: https://doi.org/10.1023/A:1012742721922