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Oxidation of I- and S2- Anions by Oxygen in Aqueous Suspensions of Silica Gel

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Abstract

Oxidation of I- and S2 - anions on the silica gel surface by atmospheric oxygen was studied at room temperature. The possibility and rate of oxidation processes are determined by the content of silica gel and oxygen in the systems. Tentative interpretation of the results is based on the assumption that a highly reactive singlet 1O2 species is formed in the oxygen ensemble on the silica surface.

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REFERENCES

  1. March, J., Advanced Organic Chemistry, New York: Wiley, 1985.

    Google Scholar 

  2. Wasserman, H.H. and Ives, J.L., Tetrahedron, 1981, vol. 37, pp. 1825-1852.

    Google Scholar 

  3. Shen, H.R., Spikes, J.D., Smith, C.J., and Kopecek, J., J. Photochem. Photobiol. A: Chem., 2000, vol. 130, pp. 1-6.

    Google Scholar 

  4. Lledias, F. and Hansberg, W., Photochem. Photobiol., 1999, vol. 70, pp. 887-892.

    Google Scholar 

  5. Solterman, A.T., Luiz, M., Biasutty, M.A., et al., J. Photochem. Photobiol. A: Chem., 1999, vol. 129, pp. 25-32.

    Google Scholar 

  6. Toutchkine, A. and Clennan, E.L., J. Am. Chem. Soc., 2000, vol. 122, pp. 1834-1835.

    Google Scholar 

  7. Figueiredo, T.L.C., Johnstone, R.A.W., Sorensen, A.P.M., et al., Photochem. Photobiol., 1999, vol. 69, pp. 517-528.

    Google Scholar 

  8. Waiblinger, F., Keck, J., Fluegge, A.P., et al., J. Photochem. Photobiol. A: Chem., 1999, vol. 126, pp. 43-49.

    Google Scholar 

  9. Tung, C.H., Wang, H., and Ying, Yu.M., J. Am. Chem. Soc., 1998, vol. 120, pp. 5179-5186.

    Google Scholar 

  10. Clennan, E.L. and Sram, J.P., Tetrahedron Lett., 1999, vol. 40, pp. 5275-5278.

    Google Scholar 

  11. Zhou, W. and Clennan, E.L., Org. Lett., 2000, vol. 2, pp. 437-440.

    Google Scholar 

  12. Nardello, V., Aubry, J.M., and Linker, T., Photochem. Photobiol., 1999, vol. 70, pp. 524-530.

    Google Scholar 

  13. Aubriet, F., Maunit, B., Courrier, B., and Muller, J.F., Rapid Commun. Mass Spectrom., 1997, vol. 11, pp. 1596-1601.

    Google Scholar 

  14. Maunit, B., Hachimi, A., Manuelly, P., et al., Int. J. Mass Spectrom. Ion Processes, 1996, vol. 156, pp. 173-187.

    Google Scholar 

  15. Herron, J.T. and Huie, R.E., Ann. N.Y. Acad. Sci., 1970, vol. 171, pp. 229-238.

    Google Scholar 

  16. Radel, S.R. and Navidi, M.H., Chemistry, New York: West, 1990.

    Google Scholar 

  17. Kepka, A.G. and Grossweiner, L.I., Photochem. Photobiol., 1973, vol. 18, pp. 49-61.

    Google Scholar 

  18. Kiselev, V.F., Poverkhnostnye yavleniya v poluprovodnikakh i dielektrikakh (Surface Phenomena in Semiconductors and Insulators), Moscow: Nauka, 1970.

    Google Scholar 

  19. Chuiko, A.A., Teor. Eksp. Khim., 1987, vol. 23, no. 5, pp. 597-618.

    Google Scholar 

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Pak, V.N., Hanson, C.D. & Coon, S.R. Oxidation of I- and S2- Anions by Oxygen in Aqueous Suspensions of Silica Gel. Russian Journal of Applied Chemistry 74, 58–62 (2001). https://doi.org/10.1023/A:1012735631066

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  • DOI: https://doi.org/10.1023/A:1012735631066

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