Skip to main content
SpringerLink
Log in

The Use of Pulse Nuclear Magnetic Resonance for Studying the Mechanism of Solvation Separation of Natural Bitumen

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

A mechanism of deasphalting and fractionation of Ashal'chinsk natural bitumen with acetone was studied by pulse NMR. The features of distribution of components of the initial material in acetone solutions in deasphalting and also structural variations in the colloidal system resulting in separation of fractions when water is added in portions to the solution were studied. The structural-group composition of the separation products was characterized on the basis of NMR and IR data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Khusnutdinov, I.Sh., Kozin, V.G., and Kopylov, A.Yu., Zh. Prikl. Khim., 1998, vol. 71, no. 8, pp. 1019–1023.

    Google Scholar 

  2. RF Patent 2 055 858.

  3. Rozental', D.A., Posadov, I.A., Popov, O.G., and Paukku, A.N., Metody opredeleniya i rascheta strukturnykh parametrov fraktsii tyazhelykh neftyanykh ostatkov: Uchebnoe posobie (Methods for Determination and Evaluation of Structural Parameters of Fractions of Heavy Petroleum Residues: A Textbook), Leningrad: Leningr. Tekhnol. Inst., 1981.

    Google Scholar 

  4. Farrar, T.G. and Becker, E.D., Pulse and Fourier Transform NMR: Introduction to Theory and Methods, New York: Academic, 1971.

    Google Scholar 

  5. Vashman, A.A. and Pronin, I.S., Yadernaya magnitnaya relaksatsiya i ee primenenie v khimicheskoi fizike (Nuclear Magnetic Relaxation and Its Application to Chemical Physics), Moscow: Nauka, 1979.

    Google Scholar 

  6. Kashaev, R.S., Tarasov, V.F., Idiyatullin, Z.Sh., et al., Prib. Tekh. Eksp., 1993, no. 1, pp. 242–243.

  7. Kashaev, R.S., Zh. Fiz. Khim., 1999, vol. 73, no. 1, pp. 1972–1977.

    Google Scholar 

  8. USSR Inventor's Certificate no. 1 583 823.

  9. Kazakova, L.P. and Krein, S.E., Fiziko-khimicheskie osnovy proizvodstva neftyanykh masel (Physicochemical Principles of Production of Petroleum Oils), Moscow: Khimiya, 1978.

    Google Scholar 

  10. Pople, J.A., Schneider, W.G., and Bernstein, H.J., High-Resolution Nuclear Magnetic Resonance, New York: McGraw-Hill, 1959.

    Google Scholar 

  11. Kalabin, G.A., Polonov, V.M., Smirnov, M.B., et al., Neftekhimiya, 1986, vol. 26, no. 4, pp. 435–463.

    Google Scholar 

  12. Botneva, T.A., Il'ina, A.A., Terskoi, Ya.A., et al., Metodicheskoe rukovodstvo po lyuminestsentno-bituminologicheskim i spektral'nym metodam issledovaniya organicheskogo veshchestva porod i neftei (A Guide for Bitumen-Luminescence and Spectral Methods for Studying Organic Substances of Rocks and Crude Oils), Moscow: Nedra, 1979.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kazan State Technological University, Kazan, Tatarstan, Russia

    V. G. Kozin, A. Yu. Kopylov & R. S. Kashaev

Authors
  1. V. G. Kozin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Yu. Kopylov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. S. Kashaev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kozin, V.G., Kopylov, A.Y. & Kashaev, R.S. The Use of Pulse Nuclear Magnetic Resonance for Studying the Mechanism of Solvation Separation of Natural Bitumen. Russian Journal of Applied Chemistry 74, 870–876 (2001). https://doi.org/10.1023/A:1012730025808

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1012730025808

Keywords

Search

Navigation