Skip to main content
Log in

Viscosity B Coefficients for Alkali–Metal Bromides in 3-Hydroxypropionitrile–Acetonitrile Mixtures at 25°C

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The viscosity B coefficients were measured for LiBr, NaBr, KBr, RbBr, CsBr, Bu4NBPh4 and Bu4NBr in 3-hydroxypropionitrile–acetonitrile mixtures over the entire composition range at 25°C. The B coefficients of these electrolytes were large and positive and were split into their respective ionic values using the method of Gill and Sharma. The ionic B coefficients were positive for all the electrolytes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. A. Sacco, A. De Giglio, A. Del'Atti, and K. G. Lawrence, Z. Phys. Chem. (Wiesbaden), 136, 145 (1983).

    Google Scholar 

  2. D. S. Gill and M. S. Chauhan, Z. Phys. Chem. (Munich) 140, 149 (1984).

    Google Scholar 

  3. K. Ibuki and M. Nakahara, J. Phys. Chem. 94, 8370 (1990).

    Google Scholar 

  4. D. S. Gill, T. I. Quickenden, and T. Zamir, Indian J. Chem. 38A, 913 (1999).

    Google Scholar 

  5. C. H. Springer, J. F. Coetzee, and R. L. Kay, J. Phys. Chem. 73, 471 (1969).

    Google Scholar 

  6. R. L. Kay, B. J. Hales, and G. P. Cunningham, J. Phys. Chem. 71, 3925 (1967).

    Google Scholar 

  7. L. Tassi, J. Chem. Soc. Faraday Trans. 1 189, 733 (1993).

    Google Scholar 

  8. F. Accascina, S. Petrucci, and R. M. Fuoss, J. Amer Chem. Soc. 81, 1301 (1959).

    Google Scholar 

  9. A. Sacco, M. D. Monica, and A. De Giglio, J. Chem. Soc. Faraday Trans. 1 79, 2631 (1983).

    Google Scholar 

  10. D. S. Gill and A. N. Sharma, J. Chem. Soc. Faraday Trans. 1 78, 475 (1982).

    Google Scholar 

  11. G. Jones and M. Dole, J. Amer. Chem. Soc. 51, 2950 (1929).

    Google Scholar 

  12. H. S. Harned and B. B. Owen, The Physical Chemistry of Electrolytic Solutions, 3rd edn. (Reinhold, New York, 1958).

    Google Scholar 

  13. R. L. Kay, T. Vituccio, C. Zawoyski, and D. F. Evans, J. Phys. Chem. 70, 2336 (1966).

    Google Scholar 

  14. H. Falkenhagen and E. L. Vernon, Phys. Z. 33, 140 (1932).

    Google Scholar 

  15. R. T. M. Bicknell, K. G. Lawrence, and D. Feakins, J. Chem. Soc. Faraday Trans. 1 76, 637 (1980).

    Google Scholar 

  16. D. Feakins, D. J. Freemantle, and K. G. Lawrence, J. Chem. Soc. Faraday Trans. 1 70, 795 (1974).

    Google Scholar 

  17. N. Martinus and C. A. Vincent, J. Chem. Soc. Faraday Trans. 1 77, 141 (1981).

    Google Scholar 

  18. A. Sacco, G. Petrella, M. D. Monica, and M. Castagnolo, J. Chem. Soc. Faraday Trans. 1 73, 1936 (1977).

    Google Scholar 

  19. J. Domenech and S. Rivera, Z. Phys. Chem. (Wiesbaden.) 136, 153 (1983).

    Google Scholar 

  20. D. S. Gill, M. S. Chauhan, and M. B. Sekhi, J. Chem. Soc. Faraday Trans. 1 78, 3461 (1982).

    Google Scholar 

  21. K. G. Lawrence, A. Sacco, A. De Giglio, and A. Del'Atti, J. Chem. Soc. Faraday Trans. 1 85, 23 (1989).

    Google Scholar 

  22. D. S. Gill, P. Singh, J. Singh, P. Singh, G. Senanayake, and G. T. Hefter, J. Chem. Soc. Faraday Trans. 1 91, 2789 (1995).

    Google Scholar 

  23. G. Petrella and A. Sacco, J. Chem. Soc. Faraday Trans. 1 74, 2070 (1978).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zamir, T., Quickenden, T.I. Viscosity B Coefficients for Alkali–Metal Bromides in 3-Hydroxypropionitrile–Acetonitrile Mixtures at 25°C. Journal of Solution Chemistry 30, 937–947 (2001). https://doi.org/10.1023/A:1012727832013

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1012727832013

Navigation