Abstract
Oxidation of phenylhydrazine by atmospheric oxygen in aqueous solution, its catalytic breakdown in the presence of Aktilen A carbon fiber, and electrochemical decomposition on a polarized carbon fiber were studied. Formation of various organic products of phenylhydrazine breakdown, remaining in solution after oxidation with air and catalytic decomposition on a carbon fiber, was studied by spectroscopy and chromatography. Feasibility of electrochemical decomposition on a carbon fiber for wastewater treatment to remove hydrazine derivatives was examined.
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REFERENCES
Grekov, A.P. and Veselov, V.Ya., Fizicheskaya khimiya gidrazina (Physical Chemistry of Hydrazine), Kiev: Naukova Dumka, 1979.
Golub, D., Oren, Y., and Soffer, A., J. Electroanal. Chem., 1987, vol. 227, nos. 1-2, pp. 41-53.
Sheveleva, I.V., Cand. Sci. Dissertation, Vladivostok, 1992.
Andonoglou, P.P., Jannakoudakis, A.D., Jannakoudakis, P.D., and Theodoridou, E., Electrochim. Acta, 1998, vol. 44, nos. 8-9, pp. 1455-1465.
Georgolios, N. and Karabinas, P., J. Electroanal. Chem., 1990, vol. 280, no. 2, pp. 403-414.
Liu, J., Zhou, W., You, T., et al., Anal. Chem., 1996, vol. 68, no. 19, pp. 3350-3353.
Zhou, W., Xu, L., Wu., M., and Wang, E., Anal. Chim. Acta, 1994, vol. 299, no. 2, pp. 189-194.
Antoniadou, S., Jannakoudakis, A.D., Jannakoudakis, P.D., and Theodoridou, E., Synth. Met., 1989, vol. 32, no. 3, pp. 309-320.
Goyal, R.N. and Srivastava, A.K., Ind. J. Chem., Ser. A., 1995, vol. 34, no. 7, pp. 506-511.
Kost, A.N. and Sagitullin, R.S., Usp. Khim., 1964, vol. 33, no. 4, pp. 361-395.
Overberger, C.G., Anselme, J.P., and Lombardino, J.G., Organic Compounds with Nitrogen–Nitrogen Bonds, New York: Roland, 1966.
Organikum. Organisch-chemisches Grundpraktikum, Berlin: VEB Deutscher Verlag, 1964.
Lisitskaya, I.G., Lazareva, L.P., Gorchakova, N.K., and Khabalov, V.V., Khim. Tekhnol. Vody, 1990, no. 12, pp. 3-6.
Canquis, G. and Genies, M., Tetrahedron Lett., 1968, vol. 32, pp. 3537-3540.
Foner, S.N. and Hudson, R.L., J. Chem. Phys., 1958, vol. 28, no. 4, pp. 719-720.
Kosower, E.R. and Huang, P.C., J. Am. Chem. Soc., 1965, vol. 87, no. 20, pp. 4645-4646.
Huang, P.C. and Kosower, E.R., J. Am. Chem. Soc., 1967, vol. 89, no. 15, pp. 3910-3911.
Korovin, N.V., Gidrazin (Hydrazine), Moscow: Khimiya, 1980.
Lin, Ch. and Bocarsly, A.B., J. Electroanal. Chem., 1991, vol. 300, nos. 1-2, pp. 325-345.
Cerpia, G. and Castillo, J.R., J. Appl. Electrochem., 1998, vol. 28, no. 1, pp. 65-70.
Isaacs, M., Aguirre, M.J., Toro-Labbe, A., et al., Electrochim. Acta, 1998, vol. 43, nos. 12-13, pp. 1821-1827.
Korovin, N.V. and Kicheev, A.G., Elektrokhimiya, 1970, vol. 6, no. 9, pp. 1330-1333.
Lazareva, L.P., Zhukova, O.S., and Artem'yanov, A.P., Elektrokhimiya, 1999, vol. 35, no. 8, pp. 1027-1029.
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Zhukova, O.S., Lazareva, L.P. & Glushchenko, V.Y. Electrochemical Decomposition of Phenylhydrazine on a Fibrous Carbon Electrode . Russian Journal of Applied Chemistry 74, 219–223 (2001). https://doi.org/10.1023/A:1012713915561
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DOI: https://doi.org/10.1023/A:1012713915561