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161Dy Mössbauer study of the endohedral metallofullerenes Dy@C n (n = 80, 82, 84)

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Abstract

Mössbauer studies of Dy@C n (n = 80, 82, 84) metallofullerenes were performed at 4.2, 9.6 and 78 K with the 161Dy (25.6 keV) resonance. The observed spectra consist of two subspectra splitted by magnetic hyperfine fields near to the full moment value of trivalent Dy. Paramagnetic relaxation is observed even at 4.2 K. The observed isomer shift is consistent with the Dy3+ state and indicates a full charge transfer to the fullerene cage.

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References

  1. S. Nagase, K. Kobayashi et al., Chem. Phys. Lett. 201 (1993) 475; K. Kobayashi and S. Nagase, Chem. Phys. Lett. 282 (1998) 325.

    Article  ADS  Google Scholar 

  2. C.-H. Park, B.O. Wells et al., Chem. Phys. Lett. 213 (1993) 196; D.M. Poirier et al., Phys. Rev. B 49 (1994) 17403.

    Article  ADS  Google Scholar 

  3. T. Pichler et al., Phys. Rev. Lett. 79 (1997) 3026.

    Article  ADS  Google Scholar 

  4. M. Nomura et al., Phys. B 208/209 (1995) 539.

    Article  MathSciNet  ADS  Google Scholar 

  5. H. Giefers et al., Carbon 37 (1999) 721.

    Article  Google Scholar 

  6. D. Sun et al., J. Phys. Chem. B 101 (1997) 3928.

    Google Scholar 

  7. W. Krätschmer et al., Nature 347 (1990) 354.

    Article  ADS  Google Scholar 

  8. R.L. Cohen and H.J. Gugenheim, Nucl. Instrum. Methods 71 (1969) 27.

    Article  Google Scholar 

  9. S. Ofer et al., Phys. Rev. A 138 (1965) 241.

    Article  ADS  Google Scholar 

  10. H.H. Wickman and I. Nowik, J. Phys. Chem. Solids 28 (1996) 2099.

    Article  Google Scholar 

  11. K. Kobayashi, S. Nagase and T. Akasaka, Chem. Phys. Lett. 261 (1996) 502.

    Article  Google Scholar 

  12. H. Giefers et al., unpublished.

  13. A.I. Chumakov, this issue.

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Authors and Affiliations

  1. St. Petersburg Nuclear Physics Institute of the Academy of Science, 188350, Gatchina, Russia

    Yu.S. Grushko, E.G. Alekseev, V.S. Kozlov & L.I. Molkanov

  2. Fachbereich Physik, Universität Paderborn, D-33095, Paderborn, Germany

    G. Wortmann, H. Giefers & K. Rupprecht

  3. State Institute of the Applied Chemistry, St. Petersburg, Russia

    M.A. Khodorkovskii

Authors
  1. Yu.S. Grushko
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  2. E.G. Alekseev
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  3. V.S. Kozlov
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  4. L.I. Molkanov
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  5. G. Wortmann
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  6. H. Giefers
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  7. K. Rupprecht
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  8. M.A. Khodorkovskii
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Grushko, Y., Alekseev, E., Kozlov, V. et al. 161Dy Mössbauer study of the endohedral metallofullerenes Dy@C n (n = 80, 82, 84) . Hyperfine Interactions 126, 121–126 (2000). https://doi.org/10.1023/A:1012659820950

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  • DOI: https://doi.org/10.1023/A:1012659820950

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