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The influence of substitution of Mn ions on quadrupole splitting of EuFeO3 perovskite oxide

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Abstract

Samples of EuFe1-xMnxO3(\(x \) =0.0–1.0) were prepared. XRD measurements show that a Jahn–Teller distortion occurs at \(x \) =0.6. As \(x \) increases, the Mössbauer spectra of the samples change from a simple six line spectrum for \(x \) =0.0 to a doublet for \(\)0.5 and QS increase from -0.02 mm/s to 1.05 mm/s for \(x \) =0.8, which is caused by the decrease of the Curie temperature and by the Jahn–Teller distortion, respectively.

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Authors
  1. Li‐Ping Li
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  2. Xiao‐Yu Song
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  3. Wen‐Hui Su
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  4. Quan Wei
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  5. Zhi‐Jian Kang
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Li, L., Song, X., Su, W. et al. The influence of substitution of Mn ions on quadrupole splitting of EuFeO3 perovskite oxide. Hyperfine Interactions 116, 167–172 (1998). https://doi.org/10.1023/A:1012650100766

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