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Mössbauer studies of heteroleptic Sn(II) derivatives

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Abstract

The heteroleptic Sn(II) derivatives, [Sn(η5-C5Me5)Cl] (1), [{Sn(η5‐C5Me4SiMe2But)} {Sn(η5‐C5Me4SiMe2But)(OSO2CF3)}] (2), [{Sn(η5‐C5Me5)}{Sn(η5‐C5Me5)(OSO2CF3)}] (3) and [(Sn{N(SiMe3)2}{OSO2CF3})2] (4), were prepared and characterized by 119Sn Mössbauer spectroscopy, as well as by other techniques such as multinuclear NMR (solution‐ and solid‐state) spectroscopy and X‐ray crystallography. The 119Sn Mössbauer spectroscopic data were in good agreement with the other solid state results rendering additional support for the elucidation of bonding and structural features of these compounds.

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Authors and Affiliations

  1. Departamento de Química, Universidade Federal de Minas Gerais, Belo Horizonte CEP, 31270‐901, MG, Brazil

    G.M. de Lima

  2. Laboratoire de Chemie Inorganique et Nucléaire INAN, NUCL, Université Catholique de Louvain, B‐1348, Louvain‐la‐Neuve, Belgium E-mail

    L.J.‐M. Pierssens & B. Mahieu

Authors
  1. G.M. de Lima
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  2. L.J.‐M. Pierssens
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  3. B. Mahieu
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de Lima, G., Pierssens, L. & Mahieu, B. Mössbauer studies of heteroleptic Sn(II) derivatives. Hyperfine Interactions 122, 327–331 (1999). https://doi.org/10.1023/A:1012643000535

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