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Spectral–Luminescence Properties of Molecular Complexes of Photoconductive Polymers with Neutral Organic Acceptors

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Journal of Applied Spectroscopy Aims and scope

Abstract

It has been found that in films of aryl– and alkyl–substituted polysilanes -- poly(methylphenylsilane) and poly(dihexylsilanes) -- the molecules of electron acceptors of tetracyanoquinodimethane, dinitrofluorenone, and trinitrofluorenone form weak complexes with charge transfer from the longest segments of the polymeric chain. The absorption and luminescence spectra of these complexes are similar to the spectra of complexes formed by the carbonyl groups of poly–N–epoxypropyl carbazole with the above acceptors and consist of wide bands situated in the visible range of wavelengths.

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REFERENCES

  1. A. V. Vannikov andA. D. Grishina, Photochemistry of Polymeric Donor-Acceptor Complexes [in Russian], Moscow (1984).

  2. P. M. Borsenberger andD. S. Weiss, Organic Photoreceptors for Imaging Systems, Marcel Dekker, New York (1993).

    Google Scholar 

  3. A. V. Vannikov,A. D. Grishina, andS. V. Novikov, Usp. Khim., 63, 107-128 (1994).

    Google Scholar 

  4. C. W. Tang, Appl. Phys. Lett., 48, 183-185 (1986).

    Google Scholar 

  5. S. Nespurek,A. Kadashchuk,Yu. Skryshevski,A. Fujii, andK. Yoshino, J. Soc. Electron. Mat. Eng., 9, 119-122 (2000).

    Google Scholar 

  6. R. G. Kepler andZ. G. Soos, in: N. S. Sariciftci (ed.), Primary Photoexcitations in Conjugated Polymers, Molecular Exciton versus Semiconductor Band Model, World Scientific, Singapore (1997), pp. 363-383.

    Google Scholar 

  7. M. Pope andC. E. Swenberg, in: Electronic Processes in Organic Crystals and Polymers, 2nd edn., New York (1999), pp. 877-901.

  8. R. D. Miller andJ. Michl, Chem. Rev., 89, 1359-1410 (1989).

    Google Scholar 

  9. R. G. Pitt,M. M. Bursey, andP. F. Rogerson, J. Am. Chem. Soc., 92, 519-522 (1970).

    Google Scholar 

  10. M. Kakimoto,H. Ueno,H. Kojima,Y. Yamaguchi, andA. Nishimura, Mat. Res., C328, 267-272 (1994).

    Google Scholar 

  11. V. M. Zaika,A. K. Kadashchuk,N. I. Ostapenko,Yu. A. Skryshevskii (Skryshevs'kii), and S. Neshpurek, Ukr. Fiz. Zh. [in Ukrainian], 45, 1246-1249 (2000).

    Google Scholar 

  12. R. I. Blyumbergas andA. I. Undzenas, Litovsk. Fiz. Sborn., 24, 97-105 (1984).

    Google Scholar 

  13. Yu. A. Cherkasov,Yu. P. Piryatinskii,Yu. N. Kirpach, andE. L. Aleksandrova, Opt. Spektrosk., 67, 351-355 (1989).

    Google Scholar 

  14. V. É. Kampar andO. Ya. Neiland, Usp. Khim., 46, 945-966 (1977).

    Google Scholar 

  15. V. É. Kampar andO. Ya. Neiland, Usp. Khim., 55, 637-651 (1986).

    Google Scholar 

  16. Yu. A. Skryshevskii,A. K. Kadashchuk, andN. I. Ostapenko, Fiz. Tverd. Tela, 42, 1505-1510 (2000).

    Google Scholar 

  17. O. Ito,M. Terazima,T. Azumi,N. Matsumoto,K. Takeda, andM. Fujino, Macromolecules, 22, 1718-1722 (1989).

    Google Scholar 

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Skryshevskii, Y.A. Spectral–Luminescence Properties of Molecular Complexes of Photoconductive Polymers with Neutral Organic Acceptors. Journal of Applied Spectroscopy 68, 593–597 (2001). https://doi.org/10.1023/A:1012565920958

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  • DOI: https://doi.org/10.1023/A:1012565920958

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