Abstract
Crystals of [Cu(o-Andp)(H2O)2] · 2H2O (where o-Andp2–is о-anisidine-N,N-di-3-propionate) were synthesized and studied using X-ray diffraction analysis. The crystals are triclinic: a= 12.063(1) Å, b= 12.483(3) Å, c= 13.586(2) Å, α = 91.29(1)°, β = 111.67(1)°, γ = 104.00(1)°, V= 1830.5(5) Å3, space group P \(\overline 1\), Z= 2, and R= 0.0528 for 5965 reflections with I≥ 2σ(I ). The two crystallographically independent complexes are isostructural. The tetragonal–bipyramidal coordination of copper(III) involves three O atoms, the N atom of the tetradentate ligand o-Andp2–, and two O atoms from water. The aminodipropionate group of the ligand (average Cu–O 1.939 Å and Cu–N 2.051 Å) and one of the coordinated water molecules (Cu–O(w) 1.991 Å) lie in the equatorial plane. The second water molecule (Cu–O(w) 2.32 Å) and the methoxy O atom of o-Andp2–(Cu–O 2.37 Å) are in the apical positions of the bipyramid.
Similar content being viewed by others
REFERENCES
Skorik, Yu.A., Neudachina, L.K., and Vshivkov, A.A., Zh. Obshch. Khim., 1999, vol. 69, no. 2, p. 296.
Skorik, Yu.A., Neudachina, L.K., Vshivkov, A.A., et al., Zh. Fiz. Khim., 1999, vol. 73, no. 12, p. 2269.
Skorik, Yu.A., Neudachina, L.K., Vshivkov, A.A., et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1998, vol. 41, no. 3, p. 119.
Skorik, Yu.A., Neudachina, L.K., Korotovskikh, E.V., and Vshivkov, A.A., Zavod. Lab., 2001, vol. 67, no. 3, p. 15.
Neudachina, L.K., Skorik, Yu.A., Gert, N.V., et al., Tezisy dokladov Vserossiiskoi konferentsii "Khimicheskii analiz veshchestv i materialov" (Proc. All-Russia Conf. "Chemical Analysis of Substances and Materials"), Moscow, 2000, p. 377.
Skorik, Yu.A., Neudachina, L.K., Vshivkov, A.A., and Mursalimova, V.Kh., Zh. Neorg. Khim., 2001, vol. 46, no. 1, p. 143.
Skorik, Yu.A., Cand. Sci. (Chem.) Dissertation, Yekaterinburg: Ural'skii Gos. Univ., 1998.
Schwarzenbach, G. and Flaschka, H., Die komplexometrische Titration, Stuttgart: F. Enke, 1965. Translated under the title Kompleksonometricheskoe titrovanie, Moscow: Khimiya, 1970.
Tomita, K., Bull. Chem. Soc. Jpn., 1961, vol. 34, no. 1, p. 297.
Mitsui, Y., Iitaka, Y., and Sakaguchi, H., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1976, vol. 32, no. 6, p. 1634.
Kamwaya, M.V. and Teoh, S.G., J. Fiz. Malays., 1984, vol. 5, no. 1, p. 1.
Polyakova, I.N., Sergienko, V.S., and Poznyak, A.L., Zh. Neorg. Khim., 1995, vol. 40, no. 11, p. 1811.
Poznyak, A.L., Antsyshkina, A.S., Sadikov, G.G., et al., Zh. Neorg. Khim., 1998, vol. 43, no. 6, p. 961.
Burshtein, I.F. and Poznyak, A.L., Zh. Neorg. Khim., 1998, vol. 43, no. 7, p. 1148.
Matović, Z.D., Pelosi, G., Ianelly, S., et al., Inorg. Chim. Acta, 1998, vol. 268, no. 2, p. 221.
Burshtein, I.F., Poznyak, A.L., and Stopolyanskaya, L.V., Zh. Neorg. Khim., 1999, vol. 44, no. 8, p. 1251.
Cremer, D. and Pople, J.A., J. Am. Chem. Soc., 1975, vol. 97, no. 6, p. 1354.
Antsyshkina, A.S., Sadikov, G.G., Poznyak, A.L., and Sergienko, V.S., Zh. Neorg. Khim., 1998, vol. 43, no. 2, p. 241.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Skorik, Y.A., Romanenko, G.V., Neudachina, L.K. et al. Diaqua[N,N-di(2-carboxyethyl)-o-anisidinato]copper(II) Dihydrate [Cu(o-Andp)(H2O)2] · 2H2O: Synthesis and Crystal Structure. Russian Journal of Coordination Chemistry 27, 796–802 (2001). https://doi.org/10.1023/A:1012519106613
Issue Date:
DOI: https://doi.org/10.1023/A:1012519106613