Abstract
The residual reorientational polarization P r(and g 31) of multicomponent lead-zirconate-titanate-based tetragonal solid solutions differing in the number of components,N, was shown to be proportional to the uniform distortion parameter δt , in contrast to the inverse proportionality within an individual system. This accounts for the nonmonotonic variation of the electromechanical coupling coefficient K p , which first rises notably with Nbut decreases in going from quinary to senary systems, while d 31increases only slightly. In light of this, the optimal electrical properties are, as a rule, offered by quinary solid solutions.
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Dantsiger, A.Y., Dudkina, S.I., Reznichenko, L.A. et al. Effect of the Number of Components on the Ferroelectric Properties of Multicomponent Solid Solutions Based on Lead Zirconate Titanate. Inorganic Materials 37, 1161–1164 (2001). https://doi.org/10.1023/A:1012501326757
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DOI: https://doi.org/10.1023/A:1012501326757