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Immobilization of Thienyl-Containing Azo Pigments on Silica Gel Surface

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Abstract

Reactions of chlorinated silica gel with thienyllithium and its derivatives gave silica gels modified by organic fragments. By successive chemical transformations of the latter immobilized thienyl-contaning azo pigments were obtained. Azo pigments can also be immobilized on silica gel surface through reactions with 2,4,6-trichloro-1,3,5-triazine. Silica gels with grafted azo pigments are characterized by high resistance to light and washing.

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REFERENCES

  1. Lisichkin, G.V., Zh. Vses. Khim. Ob-va., 1989, vol. 34, no. 3, pp. 291-297.

    Google Scholar 

  2. Tundo, P., J. Chem. Soc., Chem. Commun., 1977, pp. 641-642.

  3. Immobilised Cells and Enzymes: A Practical Approach, Woodward, J., Ed., Oxford: IRL, 1985.

    Google Scholar 

  4. Chirakadze, G.G., Saginashvili, M.G., Longurashvili, N.T., and Mkheidze, N.P., USSR Inventor's Certificate no. 1 310 413, 1985; Byull. Izobret., 1987, no. 18.

  5. Mkheidze, N.P., Apkhazava, P.N., and Chirakadze, G.G., Izv. Akad. Nauk Gruz. SSR, Ser. Khim., 1990, vol. 16, no. 2, pp. 98-103.

    Google Scholar 

  6. Mozingo, R., Harris, S.A., Wolf, D.E., and Hoffine, C.E., J. Am. Chem. Soc., 1945, vol. 67, no. 12, pp. 2092-2095.

    Google Scholar 

  7. Blatt, A.H., Gross, N., and Tristram, E.W., J. Org. Chem., 1957, vol. 22, no. 12, pp. 1588-1590.

    Google Scholar 

  8. Fillipov, A.P. and Karpenko, G.A., Teor. Eksp. Khim., 1978, vol. 14, no. 3, pp. 419-423.

    Google Scholar 

  9. Iler, R.K., The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry, New York: Wiley, 1979. Translated under the title Khimiya kremnezema, Moscow: Mir, 1982, vol. 2, pp. 866-888.

    Google Scholar 

  10. Lisichkin, G.V., Kudryavtsev, G.V., Serdan, A.A., Staroverov, S.M., and Yuffa, A.Ya., Modifitsirovannye kremnezemy v sorbtsii, katalize i khromatografii (Modified Silicas in Sorption, Catalysis, and Chromatography), Moscow: Khimiya, 1986, pp. 92-96.

    Google Scholar 

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Authors and Affiliations

  1. Georgian Technical University, ul. Kostava 77, Tbilisi, 380075, Georgia

    G. G. Chirakadze, Z. E. Geliashvili & T. O. Razmadze

Authors
  1. G. G. Chirakadze
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  2. Z. E. Geliashvili
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  3. T. O. Razmadze
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Chirakadze, G.G., Geliashvili, Z.E. & Razmadze, T.O. Immobilization of Thienyl-Containing Azo Pigments on Silica Gel Surface. Russian Journal of Organic Chemistry 37, 1013–1016 (2001). https://doi.org/10.1023/A:1012486718889

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  • DOI: https://doi.org/10.1023/A:1012486718889

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