Skip to main content
Log in

Accelerated cure of thermoset fiber composites utilizing latent cure agents

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Cure agents including micro-pulverized dicyandiamide, aliphatic amine, imidazole, dyhydrazide, and ureas have been formulated with DGEBA (diglycidyl ether of bisphenol-A) epoxides to provide preimpregnated fiberglass prepregs suitable for the rapid production of structural composites under an aggressive elevated temperature cure schedule (10 min at 110°C). Formulations have been developed utilizing in part Taguchi orthogonal experimental arrays and compared to existing chemistries. Chemical formulation properties including heat of reaction, viscosity, glass transition, process parameter determination, and impact of environmental exposure have been investigated. Formulations developed within this body of work appear to outperform current commercial systems for the production of structural composites rapidly processed at a relatively low temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. B. S. Kim, Key Engineering Materials 145 (1998) 749.

    Google Scholar 

  2. J. Spoerre, B. Wang, C. Zhang and R. S. Parnas, in Applications of Artificial Intelligence in Engineering XI Proceedings, Clearwater, FL, 1996, edited by R. A. Adey, G. Rzevski and A. K. Sunol. (Comp. Mech. Pubs Southhampton, UK) p. 49.

  3. Idem., in Third ISPE International Conference on Concurrent Engineering: Research Advances in Concurrent Engineering, CE 96, edited by M. Sobolewski and M. Fox (Technomic Pub., Lancaster, PA, USA 1996), p. 409.

    Google Scholar 

  4. J. M. Methven, Materials Tech. 9(7/8) (1994) 163.

    Google Scholar 

  5. B. T. Astrom, P. H. Larsson, P. J. Hepola and R. B. Pipes, Composites 25(8) (1994) 814.

    Google Scholar 

  6. B. Ellis, M. S. Found and J. R. Bell, J. Appl. Polym. Sci. 59 (1996) 1493.

    Google Scholar 

  7. H. Lee and K. Neville, “Handbook of Epoxy Resins” (McGraw-Hill, New York, 1967).

    Google Scholar 

  8. C. A. May (ed.), “Epoxy Resins Chemistry and Technology,” 2nd ed. (Marcel Decker Inc., New York 1988).

    Google Scholar 

  9. B. Ellis (ed.), “Chemistry and Technology of Epoxy Resins” (Blackie Academic & Professional Chapman & Hall, Glasgow, 1993).

    Google Scholar 

  10. R. Turpin and A. Green, “International SAMPE Symposium Proceedings 1991,” p.2111–2119.

  11. D. K. Hoffman, D. V. Dellar, M. L. Deviney and H. W. Schlameus, “International SAMPE Technical Conference, 1996”, p.481–494.

  12. Landec Corporation, www.landec1.com (1998).

  13. P. L. Wiggins, SAMPE Quarterly 18(1) (1986) 15.

    Google Scholar 

  14. J. D. Holbery, Master's Thesis, University of Washington, 1996.

  15. F. Lee, S. Brinkerhoff and S. McKinney, International SAMPE Symposium Proceedings (1990), p. 2202–2215.

  16. W. V. Breitigam, R. S. Bauer and C. A. May, ACS Chemtech (1993), p. 38–42.

  17. J. B. Enns and J. K. Gillham, in “Polymer Characterization,” edited by C. Craver ACS Advances in Chemistry Series 203 American Chemical Society, Washington DC, 1983), Chap. 2.

    Google Scholar 

  18. G. R. Palmese and R. L. JcCullough, J. Appl. Poly. Sci. 46 (1992) 1863.

    Google Scholar 

  19. S. S. Chang, Polymer 33 (1992) 4768.

    Google Scholar 

  20. M. S. Phadke, “Quality Engineering Using Robust Design,” Prentice-Hall, Englewood Cliffs, NJ (1989), p. 115.

    Google Scholar 

  21. C. Chmielewski, K. Jayaraman and C. A. Petty, Polymer Composites 14(3) (1988) 257.

    Google Scholar 

  22. N. L. Hancox, SAMPE Quarterly 18(2), (1986) 1.

    Google Scholar 

  23. P. L. Wiggins, ibid. 17(1) (1987) 15.

    Google Scholar 

  24. S. Simon and J. Gillham, J. Appl. Poly. Sci. 46 (1992) 1245.

    Google Scholar 

  25. R. Hinrichs and J. Thuen, Proc. Annual SAMPE Tech. Conf. 24 (1979) 557.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. K. Bordia.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Holbery, J.D., Bordia, R.K. Accelerated cure of thermoset fiber composites utilizing latent cure agents. Journal of Materials Science 36, 5301–5308 (2001). https://doi.org/10.1023/A:1012474702397

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1012474702397

Keywords

Navigation