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Reactions of Amidosulfuric Acid Salts with Formaldehyde

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Abstract

Potassium amidosulfate reacts with formaldehyde at pH 7-12 to afford a mixture of dipotassium 4-hydroxy-1,3-diazabutane-1,3-disulfonate hydrate and tripotassium 6-hydroxy-1,3,5-triazahexane-1,3,5-trisulfonate HO(CH2NSO3K) n ·H2O (n = 2, 3). The reaction of the same compounds at pH 1-3 gives diammonium 1,3,5,7-tetraazabicyclo[3.3.1]nonane-3,7-disulfonic acid sulfate dihydrate.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Moskovskii pr. 26, St. Petersburg, 198013, Russia

    G. A. Lyushnina, A. Yu. Bryukhanov, M. Turkina, K. V. Malakhov & E. L. Golod

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  1. G. A. Lyushnina
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  2. A. Yu. Bryukhanov
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  3. M. Turkina
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  4. K. V. Malakhov
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  5. E. L. Golod
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Lyushnina, G.A., Bryukhanov, A.Y., Turkina, M. et al. Reactions of Amidosulfuric Acid Salts with Formaldehyde. Russian Journal of Organic Chemistry 37, 1030–1033 (2001). https://doi.org/10.1023/A:1012443003868

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  • DOI: https://doi.org/10.1023/A:1012443003868

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