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Generation of Chloropolyfluoromethylene-1-indanyl Cations and Their Isomerization into Chloropolyfluoromethylindenyl Cations

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Abstract

Chlorooctafluoro-3-methylene-1-indanyl, 3-(chlorofluoromethylene)heptafluoro-1-indanyl, and 2- and 3-(dichloromethylene)heptafluoro-1-indanyl cations were generated from the corresponding dihalomethyleneindans in the system SbF5-SO2ClF. Isomerization of these cations yields thermodynamically more stable polyfluoromethylindenyl cations with chlorine atoms in the five-membered ring.

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REFERENCES

  1. Karpov, V.M., Platonov, V.E., and Yakobson, G.G., Tetrahedron, 1978, vol. 34, no. 21, pp. 3215-3218.

    Google Scholar 

  2. Karpov, V.M., Platonov, V.E., Chuikov, I.P., and Shchegoleva, L.N., Russ. J. Org. Chem., 1999, vol. 35, no. 1, pp. 80-84.

    Google Scholar 

  3. Karpov, V.M., Platonov, V.E., and Yakobson, G.G., Izv. Akad. Nauk SSSR, Ser. Khim., 1978, no. 11, p. 2655.

    Google Scholar 

  4. Karpov, V.M., Platonov, V.E., and Yakobson, G.G., Izv. Akad. Nauk SSSR, Ser. Khim., 1979, no. 9, pp. 2082-2087.

    Google Scholar 

  5. Karpov, V.M., Platonov, V.E., and Shchegoleva, L.N., Russ. J. Org. Chem., 1998, vol. 34, no. 11, pp. 1660-1665.

    Google Scholar 

  6. Olah, G.A. and Comisarov, M.B., J. Am. Chem. Soc., 1967, vol. 91, no. 11, pp. 2955-2961; Pozdnyakovich, Yu.V. and Shteingarts, V.D., J. Fluorine Chem., 1974, vol. 4, no. 3, pp. 283-316.

    Google Scholar 

  7. Shteingarts, V.D., Usp. Khim., 1981, vol. 50, no. 8, pp. 1407-1436.

    Google Scholar 

  8. Karpov, V.M., Platonov, V.E., Chuikov, I.P., and Yakobson, G.G., J. Fluorine Chem., 1983, vol. 22, no. 5, pp. 459-473.

    Google Scholar 

  9. Pushkina, L.N., Stepanov, A.P., Zhukov, V.S., and Naumov, A.D., Zh. Org. Khim., 1972, vol. 8, no. 3, pp. 586-597; Matthews, R.S. and Preston, W.E., J. Org. Magn. Reson., 1980, vol. 14, no. 4, pp. 258-263.

    Google Scholar 

  10. Karpov, V.M., Platonov, V.E., Stolyarova, T.A., and Yakobson, G.G., Izv. Akad. Nauk SSSR, Ser. Khim., 1981, no. 7, pp. 1586-1591.

    Google Scholar 

  11. Chuikov, I.P., Karpov, V.M., and Platonov, V.E., Izv. Ross. Akad. Nauk, Ser. Khim., 1992, no. 6, pp. 1412-1418.

    Google Scholar 

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Authors and Affiliations

  1. Siberian Division, Russian Academy of Sciences, Vorozhtsov Novosibirsk Institute of Organic Chemistry, pr. Akademika Lavrent'eva 9, Novosibirsk, 630090, Russia

    V. M. Karpov & V. E. Platonov

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  1. V. M. Karpov
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  2. V. E. Platonov
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Karpov, V.M., Platonov, V.E. Generation of Chloropolyfluoromethylene-1-indanyl Cations and Their Isomerization into Chloropolyfluoromethylindenyl Cations. Russian Journal of Organic Chemistry 37, 981–987 (2001). https://doi.org/10.1023/A:1012426500233

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