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Reaction of Platinum Fulleride C60Pt with Dihydroanthracene

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Abstract

9,10-Dihydroanthracene (C14H12 reacts with platinum fulleride C60Pt at 513-623 K under anaerobic conditions to form anthracene and hydrofullerenes identified by IR and mass spectroscopy. The Pt 4f 7/2 binding energy of platinum in the initial fulleride (72.4 eV) indicates partial charge transfer form Pt to C60, which agrees with the results of X-ray fluorescence spectroscopic study of C60Pt.

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Gol'dshleger, N.F., Shul'ga, Y.M., Roshchupkina, O.S. et al. Reaction of Platinum Fulleride C60Pt with Dihydroanthracene. Russian Journal of General Chemistry 71, 114–118 (2001). https://doi.org/10.1023/A:1012397926736

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