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Complex of Tetrachlorogermane with Dimethyl Sulfoxide and Its IR Spectral Study

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Abstract

The complex 2(Me2SO)-GeCl4 in which the hexacoordinate germanium atom is coordinated via oxygen atoms with two Me2S = O molecules was studied by IR spectroscopy. The strong doublet band with maxima at 495 and 506 cm-1 in the spectrum of the complex was assigned to stretching vibrations of the Ge-O coordination bond. Thermolysis of 2(Me2SO)·GeCl4 yields, along with the consituent molecules, polyoxymethylene, dimethyl disulfide, and trace amounts of chloromethyl methyl sulfide.

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Authors and Affiliations

  1. Siberian Division, Favorskii Irkutsk Institute of Chemistry, Irkutsk, Russia

    M. G. Voronkov, G. A. Gavrilova & S. V. Basenko

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  1. M. G. Voronkov
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  2. G. A. Gavrilova
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  3. S. V. Basenko
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Voronkov, M.G., Gavrilova, G.A. & Basenko, S.V. Complex of Tetrachlorogermane with Dimethyl Sulfoxide and Its IR Spectral Study. Russian Journal of General Chemistry 71, 210–212 (2001). https://doi.org/10.1023/A:1012391119892

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