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Electrolytic Conductivity of Potassium 2-Phenylethyneselenolate in Tetrahydrofuran and Acetonitrile

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Abstract

Potassium 2-phenylethyneselenolate is slightly dissociated in THF and to a greater extent, in acetonitrile, as demonstrated by the electrolytic conductivity data. Results on the electrochemical behavior of potassium 2-phenylethyneselenolate are used for interpretation of the reactivity of acetylene selenolates.

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REFERENCES

  1. Brandsma, L., Wijers, H.E., and Arens, J.F., Recl. Trav. Chim. Pays-Bas, 1962, vol. 81, no. 5, pp. 583-584.

    Google Scholar 

  2. Brandsma, L., Wijers, H.E., and Jonker, C., Recl. Trav. Chim. Pays-Bas, 1963, vol. 83, no. 2, p. 208.

    Google Scholar 

  3. Petrov, A.A., Radchenko, S.I., Mingaleva, K.S., Savich, I.G., and Lebedev, V.B., Zh. Obshch. Khim., 1964, vol. 34, no. 6, pp. 1899-1905.

    Google Scholar 

  4. Radchenko, S.I., Zh. Org. Khim., 1967, vol. 3, no. 10, p. 2229.

    Google Scholar 

  5. Sukhai, R.S., Verboom, W., Meijer, J., Schoufs, J.M., and Brandsma, L., Recl. Trav. Chim. Pays-Bas, 1981, vol. 100, no. 1, pp. 10-13.

    Google Scholar 

  6. Laishev, V.Z., Petrov, M.L., and Petrov, A.A., Zh. Org. Khim., 1982, vol. 18, no. 3, pp. 514-519.

    Google Scholar 

  7. Lalezari, I., Synthesis, 1984, no. 8, pp. 660-661.

  8. Ganjian, I. and Lalezari, I., J. Heterocyclic Chem., 1985, vol. 22, no. 3, pp. 857-858.

    Google Scholar 

  9. Malek-Yazdi, F. and Yalpani, M., Synthesis, 1977, no. 5, pp. 328-330.

  10. Sukhai, R.S., Song, R., and Brandsma, L., Synthesis, 1977, no. 12, pp. 888-889.

  11. Murai, T., Ezaka, T., Kando, T., and Kato, S., Chem. Commun., 1996, no. 15, pp. 1809-1810.

  12. Murai, T., Ezaka, T., and Kato, S., Bull. Chem. Soc. Jpn., 1998, vol. 71, no. 5, pp. 1193-1200.

    Google Scholar 

  13. Schuijl, P.J.W., Brandsma, L., and Arens, J.F., Recl. Trav. Chim. Pays-Bas, 1966, vol. 85, no. 8, pp. 889-894.

    Google Scholar 

  14. Murai, T., Hayasi, A., Kando, T., and Kato, S., Chem. Lett., 1993, no. 9, pp. 1469-1472.

  15. Murai, T., Kakami, K., Hayasi, A., Komuro, T., Takado, H., Fujii, M., Kando, T., and Kato, S., J. Am. Chem. Soc., 1997, vol. 119, no. 37, pp. 8592-8597.

    Google Scholar 

  16. Murai, T., Takado, H., Kakami, K., Fujii, M., Maeda, M., and Kato, S., Tetrahedron, 1997, vol. 53, no. 36, pp. 12237-12247.

    Google Scholar 

  17. Malek-Yazdi, F. and Yalpani, M., J. Org. Chem., 1976, vol. 41, no. 4, pp. 728-730.

    Google Scholar 

  18. Petrov, M.L., and Petrov, A.A., Usp. Khim., 1987, vol. 56, no. 2, pp. 267-286.

    Google Scholar 

  19. Zmitrovich, N.I., Petrov, M.L., and Petrov, A.A., Zh. Org. Khim., 1990, vol. 26, no. 1, pp. 179-184.

    Google Scholar 

  20. Ishihara, H., Yoshimi, M., and Kato, S., Angew. Chem., 1990, vol. 102, no. 5, pp. 572-573.

    Google Scholar 

  21. Abramov, M.A., Niyazymbetov, M.E., and Petrov, M.L., Zh. Obshch. Khim., 1992, vol. 62, no. 9, pp. 2138-2139.

    Google Scholar 

  22. Terent'eva, N.A., Petrov, M.L., Potekhin, K.A., Galishev, V.A., and Struchkov, Yu.T., Zh. Org. Khim., 1994, vol. 30, no. 12, pp. 1870-1874.

    Google Scholar 

  23. Zmitrovich, N.I. and Petrov, M.L., Zh. Org. Khim., 1996, vol. 32, no. 12, pp. 1870-1874.

    Google Scholar 

  24. Zmitrovich, N.I., Petrov, M.L., Potekhin, K.A., and Balasheva, E.V., Zh. Obshch. Khim., 1996, vol. 66, no. 10, pp. 1684-1687.

    Google Scholar 

  25. Petrov, M.L., Abramov, M.A., Dehaen, W., and Toppet, S., Tetrahedron Lett., 1999, vol. 40, no. 20, pp. 3903-3904.

    Google Scholar 

  26. Laishev, V.Z., Petrov, M.L., and Petrov, A.A., Zh. Org. Khim., 1982, vol. 18, no. 2, pp. 281-287.

    Google Scholar 

  27. Techniques of Electrochemistry, Eger, E. and Zalkind, A., Eds., New York: Wiley, 1973, vol. 1.

    Google Scholar 

  28. Gordon, A.J., Physical Organic Chemistry, New York: Wiley, 1976.

    Google Scholar 

  29. Maiofis, S.L., Filanovskii, B.K., and Grilikhes, M.S., Zh. Fiz. Khim., 1979, vol. 53(5), pp. 1257-1262.

    Google Scholar 

  30. Grilikhes, M.S. and Filanovskii, B.K., Kontaktnaya konduktometriya (Contact Conductometry), Leningrad: Khimiya, 1980.

    Google Scholar 

  31. Shoshina, I.A., Borodulina, E.M., Gulyaeva, L.I., Filanovskii, B.K., and Rotinyan, A.L., Elektrokhimiya, 1980, vol. 16, no. 8, pp. 1239-1242.

    Google Scholar 

  32. Ravdel', A.A. and Porai-Koshits, A.B., Zh. Prikl. Khim., 1967, vol. 40, no. 3, p. 456.

    Google Scholar 

  33. Hammett, L.R., Physical Organic Chemistry. Reaction Rates, Equilibria, and Mechanisms, New York: McGraw-Hill, 1970.

    Google Scholar 

  34. Weissberger, A., Proskauer, E.S., Riddick, J.A., and Toops, E.E., Organic Solvents. Physical Properties and Methods of Purification, New York: Interscience, 1955.

    Google Scholar 

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Rodionova, L.S., Filanovskii, B.K. & Petrov, M.L. Electrolytic Conductivity of Potassium 2-Phenylethyneselenolate in Tetrahydrofuran and Acetonitrile. Russian Journal of General Chemistry 71, 85–88 (2001). https://doi.org/10.1023/A:1012389624919

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