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1H NMR Study of cis-trans Isomerization of Rhenium(III) Binuclear Complexes in Acetone Solutions

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Abstract

The behavior of rhenium(III) binuclear complexes K2Re2Hlg8, Re2(RCOO)2Hlg4 [Hlg = Cl and Br; R = CH3, C2H5, (CH3)2CH, and (CH3)3C] in acetone solutions was studied by 1H NMR. Reaction with neutral donor ligand (H2O and hexamethylphosphoramide) induces transformation of trans-Re2(RCOO)2Hal4 to solvated cis-Re2(RCOO)2Hal4.

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Authors and Affiliations

  1. Khlopin Radium Institute, St. Petersburg, Russia

    V. A. Mikhalev

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  1. V. A. Mikhalev
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Mikhalev, V.A. 1H NMR Study of cis-trans Isomerization of Rhenium(III) Binuclear Complexes in Acetone Solutions. Russian Journal of General Chemistry 71, 1–3 (2001). https://doi.org/10.1023/A:1012388400812

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  • DOI: https://doi.org/10.1023/A:1012388400812

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