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Reaction of Triphenylbismuth Bis(arenesulfonates) with Triphenylstibine

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Abstract

Tetraphenylantimony arenesulfonates and diphenylbismuth arenesulfonates were prepared by reaction of triphenylbismuth bis(arenesulfonates) with triphenylstibine in toluene at 25°C. The crystal and molecular structure of diphenylbismuth 2,4-dimethylbenzenesulfonate was studied by single crystal X-ray diffraction. The molecules of the compound in the crystal form chains of Ph2BiOSO2C6H3Me2-2,4 fragments linked with oxygen atoms of the sulfo group of the bridging arenesulfonate ligand.

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Sharutin, V.V., Sharutina, O.K., Pavlushkina, I.I. et al. Reaction of Triphenylbismuth Bis(arenesulfonates) with Triphenylstibine. Russian Journal of General Chemistry 71, 79–82 (2001). https://doi.org/10.1023/A:1012385524010

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  • DOI: https://doi.org/10.1023/A:1012385524010

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