Abstract
Tetraphenylantimony arenesulfonates and diphenylbismuth arenesulfonates were prepared by reaction of triphenylbismuth bis(arenesulfonates) with triphenylstibine in toluene at 25°C. The crystal and molecular structure of diphenylbismuth 2,4-dimethylbenzenesulfonate was studied by single crystal X-ray diffraction. The molecules of the compound in the crystal form chains of Ph2BiOSO2C6H3Me2-2,4 fragments linked with oxygen atoms of the sulfo group of the bridging arenesulfonate ligand.
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REFERENCES
Zinov'eva, T.I., Dodonov, V.A., and Pryakhina, O.I., Abstracts of Papers, VI Konferentsiya po metalloorganicheskoi khimii (VI Conf. on Organometallic Chemistry), Nizhni Novgorod, 1995, p. 163.
Deacon, G.B., Felder, P.W., Domagala, M., Huber, F., and Rüther, R., Inorg. Chim. Acta, 1986, vol. 113, no. 1, pp. 43-48.
Straver, L.H. and Schierbeek, A.J., MolEN. Structure Determination System, Nonius B.V., 1994, vols. 1, 2.
Spek, A.L., Acta Crystallogr., Sect. A, 1990, vol. 46, no. 1, pp. 34-36.
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Sharutin, V.V., Sharutina, O.K., Pavlushkina, I.I. et al. Reaction of Triphenylbismuth Bis(arenesulfonates) with Triphenylstibine. Russian Journal of General Chemistry 71, 79–82 (2001). https://doi.org/10.1023/A:1012385524010
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DOI: https://doi.org/10.1023/A:1012385524010