Abstract
Sorption of Ni2+ions from aqueous solutions by ion exchangers differed in their chemical nature and structure was studied. Based on the endothermic curves of ice melting obtained by a differential scanning calorimetry, the amounts of freezing and non-freezing water present in free volumes (pores) of the studied ion exchangers were calculated. Comparison of results obtained from the kinetic curves of nickel ion sorption with data on differential scanning calorimetry indicates a role of structural factor in the sorption of nickel ions. It was found that, depending on the total amount of freezing and non-freezing water, the KU-2-8 sulfonated cationite is the most preferable ion exchanger for the sorption of nickel ions from aqueous solutions. Therefore, sorbent efficiency in this case is determined by its structure rather than by chemical nature.
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REFERENCES
Huxster, J.R. and Sorg, T.J., Reverse Osmosis Treatment to Remove Inorganic Contaminants from Drinking Water, EPA/600/52-87/109, Cincinnati, Ohio, USA, 1998.
Cliford, D.A., in Water Quality and Treatment: A Handbook of Community Water Supplies, New York: McGraw-Hill, 1990, 4th ed.
Li Chunhua, Technol. Water Treat., 1992, vol. 18, no. 3, p. 198.
Saldadze, K.M. and Kopylova-Valova, V.D., Kompleksoobrazuyushchie ionity (Complexing Ion Exchangers), Moscow: Khimiya, 1980.
De Silva, F.J., Essentials of Ion Exchange. Technical Sales Representative, Cherry Hill: Resin Tech. Inc., 1995.
Wei Yu, Zhongyan, Z., Yi, Y., and Zhilong, L., Technol. Water Treat., 1992, vol. 18, no. 3, p. 203.
Garnier, J.-M., Pham, M.K., Ciffroy, Ph., and Martin, J.-M., Environ. Sci. Technol., 1997, vol. 31, no. 6, p. 1597.
Zastavnyi, A.M., Giganov, G.L., Svobtsov, L.E., et al., Tsvetn. Met., 1980, no. 6, p. 59.
Zastavnyi, A.M., Aramyan, V.G., and Melikyan, E.A., Tsvetn. Met., 1984, no. 3, p. 30.
Blokhin, A.A., Semenov, M.I., Taushkanov, V.P., et al., Zh. Prikl. Khim. (Leningrad), 1986, vol. 59, no. 1, p. 53.
Komgol, E., Belfer, S., and Uritizberea, C., Desalination, 1996, vol. 104, no. 3, p. 197.
Senyavin, M.M., Ionnyi obmen v tekhnologii i analize neorganicheskikh veshchestv (Ion Exchange in Technology and Analyses of Inorganic Compounds), Moscow: Khimiya, 1980.
Blokhin, A.A., Tunin, I.M., Pervov, G.A., et al., Zh. Prikl. Khim. (Leningrad), 1989, vol. 62, no. 5, p. 981.
Blokhin, A.A., Prenas, Ya.V., Taushkanov, V.P., et al., Zh. Prikl. Khim. (Leningrad), 1989, vol. 62, no. 5, p. 985.
Verbich, S.V., Grebenyuk, V.D., Zakrevskaya, L.V., et al., Khim. Tekhnol. Vody, 1992, vol. 14, no. 2, p. 157.
Grebenyuk, V.D., Verbich, S.V., Atamanenko, I.D., and Sorokin, G.V., Kolloidn. Zh., 1993, vol. 55, no. 2, p. 3.
Grebenyuk, V.D., Sorokin, G.V., Verbich, S.V., and Zhiginas, L.Kh., Gal'vanotekh. Obrab. Poverkhn., 1996, vol. 4, no. 1, p. 53.
Helfferich, F., Ionenaustauscher (Ion Exchange), Weinheim: Verlag Chemie, 1959. Translated under the title Ionity, Moscow: Inostrannaya Literatura, 1962.
Polyanskii, N.G., Gorbunov, G.V., and Polyanskaya, N.L., Metody issledovaniya ionitov (Methods for Studying Ion-Exchangers), Moscow: Khimiya, 1976.
Schwarzenbach, G. and Flaschka, H., Die komplexometrische Titration, Stuttgard: Ferdinand Enke, 1965. Translated under the title Kompleksonometricheskoe titrovanie, Moscow: Khimiya, 1970.
Peryshkina, N.G., Sudarikova, A.I., and Soldatov, V.S., Sintez i svoistva ionoobmennykh materialov (Synthesis and Properties of Ion-Exchange Materials), Moscow: Khimiya, 1968.
Ionity: Katalog (Ion Exchanges: Catalogue), Cherkassy: NIITEKhIM, 1989.
Volfkovich, Yu.M. and Bagotsky, V.S., J. Power Sources, 1994, vol. 48, p. 327.
Vol'fkovich, Yu.M., Nauka Kubani, 2000, vol. 5, p. 26.
Zundel, G., Hydration and Intermolecular Interaction, Infrared Investigations with Polyelectrolyte Membranes, New York: Academic, 1969. Translated under the title Gidratatsiya i mezhmolekulyarnoe vzaimodeistvie, Moscow: Mir, 1972.
Tager, A.A. and Tsilipotkina, M.V., Usp. Khim., 1978, vol. 47, no. 3, p. 152.
Tsilipotkina, M.V., Sovremennye fizicheskie metody issledovaniya polimerov (Current Physical Methods for Studying Polymers), Moscow: Khimiya, 1982, p. 198.
Gregg, S. and Sing, K., Adsorption, Surface Area and Porosity, New York: Academic, 1982. Translated under the title Adsorbtsiya, udel'naya poverkhnost', poristost', Moscow: Mir, 1984.
Bryk, M.T., Zabolotskii, V.I., Atamanenko, I.D., and Dvorkina, G.A., Khim. Tekhnol. Vody, 1989, vol. 11, no. 6, p. 491.
Bryk, M.T. and Atamanenko, I.D., Khim. Tekhnol. Vody, 1990, vol. 12, no. 5, p. 398.
Pedley, D. and Tighe, B., Br. Polym. J., 1979, vol. 11, no. 3, p. 130.
Deodar, S. and Luner, Ph., in Water in Polymers, Rowland, S., Ed., Washington: American Chemical Society, 1980. Translated under the title Voda v polimerakh, Moscow: Mir, 1984, p. 273.
Atamanenko, I.D. and Ponomarev, M.I., Khim. Tekhnol. Vody, 1994, vol. 16, no. 6, p. 615.
Bryk, M.T., Nigmatullin, R.R., and Atamanenko, I.D., Dopov. Akad. Nauk Ukr. RSR, Ser. B: Geol., Geofiz., Khim. Biol., 1991, no. 9, p. 131.
Nigmatullin, R.R., Bryk, M.T., and Atamanenko, I.D., Vysokomol. Soedin., Ser. A, 1990, vol. 32, no. 8, p. 1667.
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Atamanenko, I.D., Verbich, S.V. & Kryvoruchko, A.P. Sorption of Nickel Ions from Aqueous Solutions by Ion Exchangers. Colloid Journal 63, 532–539 (2001). https://doi.org/10.1023/A:1012382515311
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DOI: https://doi.org/10.1023/A:1012382515311