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Electroreductive Coupling of Organic Halides with Aldehydes Catalyzed by Nickel(0) Complex with 2,2'-Bipyridine

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Abstract

A method of electrosynthesis of secondary alcohols from aldehydes and organic halides under the action of nickel(0) complexes is proposed. The key stage is addition of σ-complex RNi(I)bipy (bipy is 2,2'-bipyridine) to the aldehyde group.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences Kazan State University, Kazan, Tatarstan, Russia

    Yu. G. Budnikova, T. D. Keshner & Yu. M. Kargin

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  1. Yu. G. Budnikova
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  2. T. D. Keshner
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  3. Yu. M. Kargin
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Budnikova, Y.G., Keshner, T.D. & Kargin, Y.M. Electroreductive Coupling of Organic Halides with Aldehydes Catalyzed by Nickel(0) Complex with 2,2'-Bipyridine. Russian Journal of General Chemistry 71, 453–456 (2001). https://doi.org/10.1023/A:1012381707114

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  • DOI: https://doi.org/10.1023/A:1012381707114

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