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Reactions of Phenylenedioxytrihalophosphoranes with Arylacetylenes: III. Features of Reactions of 5,6-Dihalo-2-chlorobenzo[d]-1,3,2-dioxaphosphole 2,2-Dichloride with Arylacetylenes

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Abstract

According to the NMR, IR, and high-resolution mass spectra, the major products of the reactions of 5,6-dibromo-2-chlorobenzo[d]-1,3,2-dioxaphosphole 2,2-dichloride with arylacetylenes are 4-aryl-6,7-dibromo-2-chloro-5,6-benzo[e]-1,2-oxaphosphorin-3-ene 2-oxides. The steric structure of one of the hydrolysis products, 2-hydroxy-6,7-dibromo-4-phenyl-5,6-benzo[e]-1,2-oxaphosphorin-3-ene 2-oxide, was studied by single crystal X-ray diffraction.

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  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    V. F. Mironov, R. R. Petrov, A. A. Shtyrlina, A. T. Gubaidullin, I. A. Litvinov, R. Z. Musin & A. I. Konovalov

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  1. V. F. Mironov
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  2. R. R. Petrov
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  3. A. A. Shtyrlina
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  4. A. T. Gubaidullin
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  5. I. A. Litvinov
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  6. R. Z. Musin
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  7. A. I. Konovalov
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Mironov, V.F., Petrov, R.R., Shtyrlina, A.A. et al. Reactions of Phenylenedioxytrihalophosphoranes with Arylacetylenes: III. Features of Reactions of 5,6-Dihalo-2-chlorobenzo[d]-1,3,2-dioxaphosphole 2,2-Dichloride with Arylacetylenes. Russian Journal of General Chemistry 71, 67–74 (2001). https://doi.org/10.1023/A:1012381423101

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