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Synthesis of Dimethyl (m-Carboran-9-yl)phosphonate and Dimethyl (p-Carboran-2-yl) Phosphonate by Palladium-catalyzed Cross Coupling of 9-I-m- and 2-I-p-Carboranes with Dimethyl Hydrogen Phosphite

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Abstract

Dimethyl (m-carboran-9-yl)- and (p-carboran-2-yl)phosphonates were prepared by (Ph3)4Pd-catalyzed cross coupling of 9-I-m- and 2-I-p-carboranes with dimethyl hydrogen phosphite in the presence of triethylamine.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    L. I. Zakharkin, V. V. Guseva & V. A. Ol'shevskaya

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  1. L. I. Zakharkin
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  2. V. V. Guseva
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  3. V. A. Ol'shevskaya
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Zakharkin, L.I., Guseva, V.V. & Ol'shevskaya, V.A. Synthesis of Dimethyl (m-Carboran-9-yl)phosphonate and Dimethyl (p-Carboran-2-yl) Phosphonate by Palladium-catalyzed Cross Coupling of 9-I-m- and 2-I-p-Carboranes with Dimethyl Hydrogen Phosphite. Russian Journal of General Chemistry 71, 903–904 (2001). https://doi.org/10.1023/A:1012379317959

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  • DOI: https://doi.org/10.1023/A:1012379317959

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