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Synthesis and Some Transformations of Complex Salts of Bis-o-dicarbollyliron(II), -cobalt(II), and -nickel(II)

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Abstract

The complex salts [(o-C2B9H11)2M3+]2M'2+·4bipy, where M = Fe, Co, or Ni, M' = Fe, Co, Ni, Cu, Mn (M ≠ M'), and bipy is 2,2'-bipyridyl, were synthesized. The salts with M = Ni decompose to give 3-(2,2'-bipyridyl)-3,1,2-nickelacarborane, when refluxed in alcohol, and to give 2-(2,2'-bipyridyl)-2,1,7-nickel acarborane, when refluxed in dodecane (216°C).

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Authors and Affiliations

  1. Institute of Physical Organic Chemistry, Academy of Sciences of Belarus, Minsk, Belarus

    Z. P. Zubreichuk, A. A. Erdman, A. A. Ivko & N. A. Maier

  2. Institute of New Material Chemistry, Academy of Sciences of Belarus, Minsk, Belarus

    Z. P. Zubreichuk, A. A. Erdman, A. A. Ivko & N. A. Maier

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  1. Z. P. Zubreichuk
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  2. A. A. Erdman
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  3. A. A. Ivko
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  4. N. A. Maier
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Zubreichuk, Z.P., Erdman, A.A., Ivko, A.A. et al. Synthesis and Some Transformations of Complex Salts of Bis-o-dicarbollyliron(II), -cobalt(II), and -nickel(II). Russian Journal of General Chemistry 71, 531–534 (2001). https://doi.org/10.1023/A:1012370832130

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