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Emission Properties of the Plasma in Mixtures of Helium with Diethylzinc and Hydrogen Selenide Vapors

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Abstract

The emission properties in the range 200-600 nm of the low-temperature plasma in mixtures of He with Et2Zn and H2Se vapors were studied. The spectrum of emission accompanying decomposition of Et2Zn includes 26 identified lines of Zn atoms and strong emission of electronically excited CH* radicals, and in the case of decomposition of H2Se two emission lines of Se atoms and an emission band of SeH* radicals are observed. The rate constants of quenching of the levels He 4d 3 D 2,1 and 3p 1 P 1 on introduction into the He plasma of Et2Zn and H2Se vapors were determined; Et2Zn is a stronger quenching agent than H2Se. Analytical lines allowing monitoring of ZnSe film deposition were selected. Direct plasmochemical decomposition of mixtures of Et2Zn with H2Se results in growth of textured ZnSe(cub) layers with substantial inclusions of the hexagonal phase and with carbon-containing inclusions. The photoluminescence spectra of the films obtained exhibit a strong edge band at 460 nm, overlapping with a strong self-activated band centered at 540 nm.

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REFERENCES

  1. Gribov, B.G., Domrachev, G.A., Zhuk, B.V., Kaverin, B.S., Kozyrkin, B.I., Mel'nikov, V.V., and Suvorova, O.N., Osazhdenie plenok i pokrytii razlozheniem metalloorganicheskikh soedinenii (Deposition of Films and Coatings by Decomposition of Organometallic Compounds), Razuvaev, G.A., Ed., Moscow: Nauka, 1981.

    Google Scholar 

  2. Zhuk, B.V., Usp. Khim., 1985, vol. 54, no. 8, pp. 1312-1334.

    Google Scholar 

  3. Bregadze, V.I., Golubinskaya, L.M., and Usyatinskii, A.Ya., Metalloorg. Khim., 1988, vol. 1, no. 3, pp. 517-533.

    Google Scholar 

  4. Segui, Y., Carrere, F., and Bui, A., Thin Solid Films, 1982, vol. 92, no. 4, pp. 303-307.

    Google Scholar 

  5. Carrere, F., Segui, Y., and Moret, B., Int. Chim., 1983, no. 234, pp. 107-109.

  6. Pande, K.P. and Seabaugh, A.C., J. Electrochem. Soc., 1984, vol. 131, no. 6, pp. 1357-1359.

    Google Scholar 

  7. Dobrynin, A.V., Zorina, E.N., Popova, T.O., Neustroev, S.A., and Sokolov, E.B., Khim. Vys. Energ., 1979, vol. 13, no. 2, pp. 161-164.

    Google Scholar 

  8. Sato, M., J. Appl. Phys., 1995, vol. 78, no. 3, pp. 2123-2125.

    Google Scholar 

  9. Sato, M., Appl. Phys. Lett., 1996, vol. 68, no. 7, pp. 935-937.

    Google Scholar 

  10. Tokeda, T., Wakahara, A., Noda, S., and Sosaki, A., J. Cryst. Growth, 1997, vol. 173, nos. 3–4, pp. 237-243.

    Google Scholar 

  11. Wang, J., Zhu, Z., Park, K.T., Higara, K., and Yao, T., J. Electron. Mater., 1997, vol. 26, no. 3, pp. 232-236.

    Google Scholar 

  12. Yasui, K., Iizuka, K., Harada, T., and Akahane, T., Jpn. J. Appl. Phys., Part 1, 1997, vol. 36, no. 7B, pp. 4953-4958.

    Google Scholar 

  13. Yasuda, T., Hata, K., Mizuta, M., and Kukimoto, H., J. Cryst. Growth, 1989, vol. 96, no. 4, pp. 979-981.

    Google Scholar 

  14. Matumoto, T., Chen, H., Kasabitaki, N., Maekama, Y., and Aozasa, M., Mem. Fac. Eng. Osaka City Univ., 1993, no. 34, pp. 25-32.

  15. Fujiwa, H., Nabeta, T., Kiryu, H., and Shimizu, I., Jpn. J. Appl. Phys., Part 1, 1994, vol. 33, no. 7B, pp. 4381-4384.

    Google Scholar 

  16. Yamamoto, K. and Taguchi, T., Mem. Fac. Eng. Yamaguchi Univ., 1995, vol. 45, no. 2, pp. 311-335.

    Google Scholar 

  17. Taudt, W., Wachtendorf, B., Samerlander, F., Hamaden, H., Lampe, S., and Heuken, M., J. Electron. Mater., 1995, vol. 24, no. 11, pp. 1671-1675.

    Google Scholar 

  18. Morimoto, K., J. Cryst. Growth, 1996, vol. 159, nos. 1-4, pp. 317-320.

    Google Scholar 

  19. Taudt, W., Hardt, A., Lampe, S., Hamaden, H., and Heuken, M., J. Cryst. Growth, 1997, vol. 170, nos. 1-4, pp. 491-496.

    Google Scholar 

  20. Striganov, A.R. and Odintsova, G.A., Tablitsy spektral'nykh linii atomov i ionov: Spravochnik (Tables of Spectral Lines of Atoms and Ions: Handbook), Moscow: Energoizdat, 1982.

    Google Scholar 

  21. Zaidel', A.N., Prokof'ev, V.K., Raiskii, S.M., Slavnyi, V.A., and Shreider, E.Ya., Tablitsy spektral'nykh linii: Spravochnik (Tables of Spectral Lines: Handbook), Moscow: Nauka, 1977.

    Google Scholar 

  22. Tel'noi, V.I. and Rabinovich, I.B., Usp. Khim., 1980, vol. 49, no. 7, pp. 1137-1173.

    Google Scholar 

  23. Hetzlier, C.W., Boreman, R.W., and Burns, K., Phys. Rev., 1935, vol. 48, no. 5, pp. 656-659.

    Google Scholar 

  24. Moore, C.E., in Atomic Energy Levels, Circular of the National Bureau of Standards, 1952, no. L67, vol. 2.

  25. Balkis, T., Gaines, A.F., Ozgen, G., Ozgen, I.T., and Flowers, M.C., J. Chem. Soc., Faraday Trans. 2, 1976, vol. 72, no. 3, pp. 524-527.

    Google Scholar 

  26. Spetsial'nyi fizicheskii praktikum (Special Practical Course of Physics), Moscow: Mosk. Gos. Univ., 1977, part 2, p. 180.

  27. Creber, D.K. and Bancroft, G.M., Inorg. Chem., 1980, vol. 19, no. 3, pp. 643-648.

    Google Scholar 

  28. Slovetskii, D.I., Mekhanizmy khimicheskikh reaktsii v neravnovesnoi plazme (Mechanisms of Chemical Reactions in Nonequilibrium Plasma), Moscow: Nauka, 1980.

    Google Scholar 

  29. Razov, E.N., Korotysheva, E.E., Zhuk, B.V., Kaverin, B.S., and Rybnikov, V.V., Metalloorg. Khim., 1988, vol. 1, no. 3, pp. 586-591.

    Google Scholar 

  30. Sheverdina, N.I. and Kocheshkov, K.A., Metody elementoorganicheskoi khimii. Tsink. Kadmii (Methods of Organometallic Chemistry. Zinc. Cadmium), Moscow: Nauka, 1974, p. 14.

    Google Scholar 

  31. Devyatykh, G.G. and Churbanov, M.F., Vysokochistye khal'kogenidy (High-Purity Chalcogenides), Nizhny Novgorod: Nizhegorod. Univ., 1997, pp. 186-189.

    Google Scholar 

  32. Gurvich, L.V., Karachevtsev, G.V., Kondrat'ev, V.N., Lebedev, Yu.A., Medvedev, V.A., Potapov, V.K., and Khoddeev, Yu.S., Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu (Dissociation Energies of Chemical Bonds. Ionization Potentials and Electron Affinity), Moscow: Nauka, 1974.

    Google Scholar 

  33. Kozlov, O.V., Elektricheskii zond v plazme (Electric Probe in Plasma), Moscow: Atomizdat, 1969, pp. 90, 190.

    Google Scholar 

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhni Novgorod, Russia

    A. M. Ob'edkov, G. A. Domrachev, E. Yu. Korovina & E. N. Razov

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  1. A. M. Ob'edkov
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  2. G. A. Domrachev
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  3. E. Yu. Korovina
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  4. E. N. Razov
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Ob'edkov, A.M., Domrachev, G.A., Korovina, E.Y. et al. Emission Properties of the Plasma in Mixtures of Helium with Diethylzinc and Hydrogen Selenide Vapors. Russian Journal of General Chemistry 71, 865–872 (2001). https://doi.org/10.1023/A:1012367015233

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