Abstract
Phosphorylation of calix[4]resorcinolarenes with PCl3 yields cyclic phosphorochloridites. Cavitands containing cyclic phosphorochloridite fragments in the upper rim are readily oxidized with SO2Cl2 to the corresponding phosphorochloridates and take up four equivalents of sulfur on heating to form cyclic phosphorochloridothioates.
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Nikolaeva, I.L., Burilov, A.R., Kharitonov, D.I. et al. Cyclic Phosphorochloridites, Phosphorochloridates, and Phosphorochloridothioates Based on Calix[4]resorcinolarenes. Russian Journal of General Chemistry 71, 379–382 (2001). https://doi.org/10.1023/A:1012361102571
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DOI: https://doi.org/10.1023/A:1012361102571