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Chemistry of Dioxacycloalkanes: VII. Synthesis and Properties of Substituted 1,3-Dioxolanes Derived from Carbocyclic Aldehydes

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Abstract

Reactions of 3-cyclohexenecarbaldehyde, 6-methyl-3-cyclohexenecarbaldehyde, bicyclo[2.2.1]-hept-5-ene-endo-2-carbaldehyde, benzaldehyde with 1,2-propanediol, 3-chloro-1,2-propanediol gavethe corresponding 2,4-substituted 1,3-dioxolanes. Their reactions with peroxyacetic acid, bromine, dichloro-carbene, and nucleophiles were studied. The effect of the substituents in the diol and aldehyde on their relative reactivity is discussed.

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  1. Academy of Sciences of Azerbaidjan, Institute of Polymeric Materials, ul. S. Vurguna 124, Sumgait, 373204, Azerbaidjan

    A. Kh. Kerimov

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Kerimov, A.K. Chemistry of Dioxacycloalkanes: VII. Synthesis and Properties of Substituted 1,3-Dioxolanes Derived from Carbocyclic Aldehydes. Russian Journal of Organic Chemistry 37, 136–140 (2001). https://doi.org/10.1023/A:1012350122851

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