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Reaction of Grignard Compounds with 4-Chloro-2-methyl-3-butyn-2-ol in Diethyl Ether Equivalents

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Abstract

Reactions of RMgX·THF complexes with 4-chloro-2-methyl-3-butyn-2-ol in aromatic hydrocarbons were studied. The complexes formed by arylmagnesium halides require the presence of anisole for the reaction to occur. 4-Chloro-2-methyl-3-butyn-2-ol can be synthesized by reaction of 2-methyl-3-butyn-2-ol with sodium hypochloride in the two-phase system water-benzene.

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Authors and Affiliations

  1. Ministry of Science and Academy of Sciences of Kazakhstan, Institute of Organic Synthesis and Coal Chemistry, ul. 40 let Kazakhstana 1, Karaganda, 470061, Kazakhstan

    S. A. Shchelkunov, O. A. Sivolobova, S. O. Mataeva, D. B. Minbaev & Z. M. Muldakhmetov

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  1. S. A. Shchelkunov
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  2. O. A. Sivolobova
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  3. S. O. Mataeva
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  4. D. B. Minbaev
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  5. Z. M. Muldakhmetov
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Shchelkunov, S.A., Sivolobova, O.A., Mataeva, S.O. et al. Reaction of Grignard Compounds with 4-Chloro-2-methyl-3-butyn-2-ol in Diethyl Ether Equivalents. Russian Journal of Organic Chemistry 37, 5–8 (2001). https://doi.org/10.1023/A:1012348627878

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  • DOI: https://doi.org/10.1023/A:1012348627878

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