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First Representatives of Stable Phosphoranes Derived from Bicyclophosphorylated Carbohydrates

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Abstract

1,2-O-Isopropylidene-α-D-glucofuranose 3,5,6-phosphite was stidied in reactions with α-dicarbonyl compounds. Reagents with the electron-acceptor halogen atom form with the former stable phosphoranes, while unsubstituted α-dicarbonyl compounds, the corresponding normal phosphates.

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Sychev, V.A., Koroteev, M.P., Dzgoeva, Z.M. et al. First Representatives of Stable Phosphoranes Derived from Bicyclophosphorylated Carbohydrates. Russian Journal of General Chemistry 71, 188–190 (2001). https://doi.org/10.1023/A:1012330901237

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  • DOI: https://doi.org/10.1023/A:1012330901237

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