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Thermochemical Study of Salts of Oxygen-containing Acids in the Gas Phase: VI. Barium Metaborates

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Abstract

Vapor formation in the BaO-B2O3 system was studied by high-temperature mass spectrometry. The equilibrium reactions with participation of gaseous barium metaborates were determined. The standard enthalpies of formation of gaseous BaB2O4(g) and BaBO2(g) of -1424 ± 28 and 598 ± 15 kJ mol-1, respectively, were evaluated.

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REFERENCES

  1. Lopatin, S.I., Semenov, G.A., and Pilyugina, T.S., Zh. Obshch. Khim., 2000, vol. 70, no. 10, pp. 1590-1592.

    Google Scholar 

  2. Blackburn, P.E. and Buchler, A., J. Phys. Chem., 1965, vol. 69, no. 12, pp. 4250-4255.

    Google Scholar 

  3. Gusarov, A.V., Teplofiz. Vys. Temp., 1970, vol. 8, no. 6, pp. 1186-1191.

    Google Scholar 

  4. Il'in, M.K., Makarov, A.V., and Nikitin, O.T., Vestn. Mosk. Gos. Univ., Ser. 2: Khimiya, 1974, vol. 15, no. 4, pp. 436-438.

    Google Scholar 

  5. Kou, T. and Asano, M., High Temp. Sci., 1987, vol. 24, no. 1, pp. 1-20.

    Google Scholar 

  6. Asano, M. and Kou, T., J. Chem. Thermodyn., 1988, vol. 20, no. 11, pp. 1149-1156.

    Google Scholar 

  7. Asano, M. and Kou, T., J. Chem. Thermodyn., 1990, vol. 22, no. 12, pp. 1223-1230.

    Google Scholar 

  8. Asano, M. and Kou, T., J. Chem. Thermodyn., 1989, vol. 21, no. 8, pp. 837-845.

    Google Scholar 

  9. Asano, M. and Kou, T., High Temp. Sci., 1990, vol. 29, no. 2, pp. 171-187.

    Google Scholar 

  10. Stolyarova, V.L. and Seetharaman, S., Vacuum, 1998, vol. 49, no. 3, pp. 161-165.

    Google Scholar 

  11. Buchler, A. and Berkowitz-Mattuck, J.B., J. Chem. Phys., 1963, vol. 39, no. 2, pp. 286-291.

    Google Scholar 

  12. Lopatin, S. I., Zh. Obshch. Khim., 1999, vol. 69, no. 9, pp. 1417-1420.

    Google Scholar 

  13. Komarov, S.A., Cand. Sci. (Chem.) Dissertation, Moscow, 1979.

  14. Ugarov, V.V., Ezhov, Yu.S., and Rambidi, N.G., J. Mol. Struct., 1975, vol. 25, no. 3, pp. 357-367.

    Google Scholar 

  15. Ezhov, Yu.S. and Komarov, S.A., J. Mol. Struct., 1978, vol. 50, no. 2, pp. 305-312.

    Google Scholar 

  16. Ogden, J.S. and Williams, S.J., J. Chem. Soc., Dalton Trans., 1981, no. 2, pp. 456-462.

    Google Scholar 

  17. Shapovalov, A.M., Shevel'kov, V.F., and Mal'tsev, A.A., Zh. Strukt. Khim., 1973, vol. 14, no. 3, pp. 560-561.

    Google Scholar 

  18. Baranovskii, V.I., Lopatin, S.I., and Sizov, V.V., Zh. Obshch. Khim., 2000, vol. 70, no. 11, pp. 1766-1771.

    Google Scholar 

  19. Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu: Spravochnik (Dissociation Energies. Ionization Potentials and Electron Affinities: Handbook), Kondrat'ev, V.N., Ed., Moscow: Nauka, 1974.

    Google Scholar 

  20. Paule, R.C. and Mandel, J., Pure Appl. Chem., 1972, vol. 31, no. 3, pp. 371-394.

    Google Scholar 

  21. Termodinamicheskie svoistva individual'nykh veshchestv: Spravochnik (Thermodynamic Properties of Individual Substances, Handbook), Glushko, V.P., Ed., Moscow: Nauka, 1981, vol. 3, issue 2.

    Google Scholar 

  22. Termodinamicheskie svoistva individual'nykh veshchestv: Spravochnik (Thermodynamic Properties of Individual Substances, Handbook), Glushko, V.P., Ed., Moscow: Nauka, 1982, vol. 4, issue 1.

    Google Scholar 

  23. Konovalov, S.P. and Solomonik, V.G., Zh. Strukt. Khim., 1985, vol. 26, no. 1, pp. 15-21.

    Google Scholar 

  24. Solomonik, V.G., Marenich, A.V., and Sliznev, V.V., Koord. Khim., 1998, vol. 24, no. 7, pp. 488-498.

    Google Scholar 

  25. Charkin, D.O., McKey, M.L., and Charkin, O.P., Zh. Neorg. Khim., 1998, vol. 43, no. 10, pp. 1694-1709.

    Google Scholar 

  26. Solomonik, V.G. and Marenich, A.V., Zh. Strukt. Khim., 1999, vol. 40, no. 3, pp. 431-443.

    Google Scholar 

  27. Zakharov, A.V., Girichev, G.V., and Shlykov, S.A., Abstracts of Papers, II Mezhdynarodnaya nauchnotekhnicheskaya konferentsiya [Aktual'nye problemy khimii i khimicheskoi tekhnologii, Khimiya-99] (II Int. Scientific and Technical Conf. [Urgent Problems of Chemistry and Chemical Engineering, Chemistry-99]), Ivanovo, 1999, p. 95.

  28. Semenov, G.A., Fokina, L.A., and Mouldagalieva, R.A., J. Nucl. Mater., 1994, vol. 210, no. 2, pp. 167-171.

    Google Scholar 

  29. Alikhanyan, A.S., Steblevskii, A.V., Gorgoraki, V.I., and Sokolova, I.D., Dokl. Akad. Nauk. SSSR, 1975, vol. 222, no. 3, pp. 629-632.

    Google Scholar 

  30. Zaitsev, A.I., Korolev, N.V., and Mogutnov, B.M., Teplofiz. Vys. Temp., 1989, vol. 27, no. 3, pp. 465-471.

    Google Scholar 

  31. Powder Diffraction File, Int. Diffr. Data, 1992.

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Authors and Affiliations

  1. Research Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russia

    S. I. Lopatin, G. A. Semenov & S. M. Shugurov

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  1. S. I. Lopatin
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  2. G. A. Semenov
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  3. S. M. Shugurov
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Lopatin, S.I., Semenov, G.A. & Shugurov, S.M. Thermochemical Study of Salts of Oxygen-containing Acids in the Gas Phase: VI. Barium Metaborates. Russian Journal of General Chemistry 71, 61–66 (2001). https://doi.org/10.1023/A:1012329406263

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