Abstract
The sorption and structural parameters and thermal stability of montmorillonite pillared by Cr(III) polyhydroxocomplexes and heteronuclear Cr(III)–Cu(II) polyhydroxocomplexes were investigated. It was shown that the introduction of intercalating Cr(III) and Cr(III)–Cu(II) agents into the montmorillonite increased the value of the first basal reflection (d 001) up to 1.85 nm in the first case and up to 1.98 nm, in the second. The dependence of the values of d 001and specific surface area on the OH–/Cr3+ratio was found, which is retained during the calcination of the samples up to 500–800°C. The sorption ability of the prepared samples with respect to acetone, ethanol, benzene, toluene, and water was investigated.
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Rat'ko, A.I., Bondareva, G.V., Panasyugin, A.S. et al. Adsorption and Structural Properties of Montmorillonite Pillared by Cr(III) and Cr(III)–Cu(II) Hydroxocomplexes. Colloid Journal 63, 615–618 (2001). https://doi.org/10.1023/A:1012307320763
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DOI: https://doi.org/10.1023/A:1012307320763