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Thermal Decomposition of Cadmium Thiourea Coordination Compounds

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Abstract

Thermal decomposition of cadmium thiourea coordination compounds was considered. Cadmium sulfide is the final product for all the compounds, whereas the composition of other products of the thermolysis substantially depends on the nature of the acido ligand or the outer-sphere anion. Thermal stability parameters of the coordination compounds under study and effective activation energies of their thermolysis were determined, and a mechanism of the thermolysis was proposed.

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Semenov, V.N., Naumov, A.V. Thermal Decomposition of Cadmium Thiourea Coordination Compounds. Russian Journal of General Chemistry 71, 495–499 (2001). https://doi.org/10.1023/A:1012306512566

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