Abstract
The small-angle scattering from xerogels represents a superposition of two components: the scattering from large irregularities—the aggregates of particles, which predominates at the smallest angles, and the scattering from smaller irregularities—pores, which predominates at the comparatively large angles. These contributions to scattering are subdivided, and the parameters of the porous structure are determined. The found values of parameters agree with those obtained by adsorption and other methods. The study of the mass-transfer processes showed that their main regularities are similar to those earlier observed for carbon adsorbents; however, in xerogels these processes proceed much faster.
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REFERENCES
Plavnik, G.M. and Puryaeva, T.P., Zh. Fiz. Khim., 1997, vol. 71, no. 8, p. 1460.
Plavnik, G.M. and Puryaeva, T.P., Zh. Fiz. Khim., 1997, vol. 71, no. 11, p. 2036.
Plavnik, G.M., Purjaeva, T.P., and Chrustaleva, G.N., Colloids Surf. A, 1999, vol. 160, p. 123.
Dubinin, M.M., Usp. Khim., 1955, vol. 24, no. 1, p. 3.
Kiselev, A.V., in Metody issledovaniya struktury vysokodispersnykh i poristykh tel (Methods for Studying Structure of Highly Disperse and Porous Solids), Moscow: Akad. Nauk SSSR, 1958, p. 47.
Kontorovich, S.I., Lavrova, K.A., Plavnik, G.M., and Rehbinder, P.A., Kolloidn. Zh., 1973, vol. 35, no. 5, p. 935.
Lederer, K., Hammel, R., Schurz, J., and Janzon, J., Monatsh. Chem., 1972, vol. 103, p. 1299.
Iler, R.K., Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry, New York: Wiley, 1979. Translated under the title Khimiya kremnezema, Moscow: Mir, 1982, vol. 2, p. 1127.
Ramsay, J.D.F. and Wing, G., J. Colloid Interface Sci., 1991, vol. 141, no. 2, p. 475.
Alekseev, V.L. and Evmenenko, G.A., Kolloidn. Zh., 1999, vol. 61, no. 6, p. 725.
Neimark, I.E., Sinteticheskie mineral'nye adsorbenty i nositeli katalizatorov (Synthetic Mineral Adsorbents and Catalyst Supports), Kiev: Nauk. Dumka, 1982, p. 40.
Eroshenko, V.A. and Fadeev, A.Yu., Ross. Chem. Zh., 1996, vol. 40, no. 1, p. 92.
Plavnik, G.M., Kristallografiya, 1994, vol. 39, no. 4, p. 600.
Svergun, D.I. and Feigin, L.A., Rentgenovskoe i neitronnoe malouglovoe rasseyanie (X-ray and Neutron Small-Angle Scattering), Moscow: Nauka, 1986, p. 278.
Plavnik, G.M., Puryaeva, T.P., and Stekli, Kh.F., Zh. Fiz. Khim., 1988, vol. 72, no. 7, p. 1288.
Plavnik, G.M. and Puryaeva, T.P., Kolloidn. Zh., 2000, vol. 62, no. 4, p. 519.
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Plavnik, G.M., Puryaeva, T.P. SAXS Study of the Porous Structure and Mass-Transfer in Xerogels. Colloid Journal 63, 599–606 (2001). https://doi.org/10.1023/A:1012303219854
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DOI: https://doi.org/10.1023/A:1012303219854