Skip to main content
Log in

Reaction of 4,4-Dimethyl-1,3-dioxane with Dinitriles

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The reaction of 4,4-dimethyl-1,3-dioxane with bis(2-cyano)diethyl ether or 1,2-di(beta-cyanoethoxy)ethane yields the corresponding bis[2-(4,4-dimethyl-5,6-dihydro-2-oxazinyl)]diethyl ether and 1,2-di{beta-[2-(4,4-dimethyl-5,6-dihydro-2-oxazinyl)]ethoxy}ethane which are readily hydrolyzed under the action of aqueous alkali to give 3-methyl-3-amino-1-butanol.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Smith, M.E. and Adkins, H., J. Am. Chem. Soc., 1938, vol. 60, no. 2, pp. 407-409.

    Google Scholar 

  2. Meyers, A.I., Nabeya, A., Adickes, H.W., and Politzer, I.R., J. Am. Chem. Soc., 1969, vol. 91, no. 3, pp. 763-764; Meyers, A.I., Nabeya, A.I., Adickes, H.W., Politzer, I.R., Malone, G.R., Kovelesky, A.C., Nolen, R.L., and Portnoy, R.C., J. Org. Chem., 1973, vol. 38, no. 1, pp. 36-56.

    Google Scholar 

  3. Kalyuskii, A.R., Kuznetsov, V.V., Posashkova, S.E., and Gren', A.I., Russian Inventor's Certificate no. 1 705 290, 1992, Byull. Izobret., 1992, no. 2.

  4. Kuznetsov, V.V., Kalyuskii, A.R., and Gren', A.I., Zh. Org. Khim., 1995, vol. 31, no. 11, pp. 1667-1670.

    Google Scholar 

  5. Gren, A.I. and Kuznetsov, V.V., Abstracts of Papers, IXth European Symp. on Organic Chemistry, Warsaw, 1995, report PA 46.

  6. Zil'berman, E.N., Reaktsii nitrilov (Reactions of Nitriles), Moscow: Khimiya, 1972, pp. 251-288.

    Google Scholar 

  7. Gridnev, I.D. and Gridneva, N.A., Usp. Khim., 1995, vol. 64, no. 11, pp. 1091-1105.

    Google Scholar 

  8. Rakhmankulov, D.L., Karakhanov, R.A., Zlotskii, S.S., Kantor, E.A., Imashev, U.B., and Syrkin, A.M., Tekhnologiya organicheskikh veshchestv {cm(Technology of Organic Compounds)}, vol. 5: Khimiya i tekhnologiya 1,3-dioksatsikloalkanov (Chemistry and Technology of 1,3-Dioxacycloalkanes), Moscow: VINITI, 1979.

    Google Scholar 

  9. Kuznetsov, V.V., Abstracts of Papers, XII Mezhdunarodnaya konferentsiya po proizvodstvu i primeneniyu khimicheskikh reaktivov i reagentov “Reaktiv-99” (XII Int. Conf. on the Production and Use of Chemicals “Reagent-99”), Ufa, 1999, p. 62.

  10. Kalyuskii, A.R. and Posashkova, S.E., Available from VINITI, 1988, Moscow, no. 8456-V88, Ref. Zh. Khim., 1989, 9Zh115.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuznetsov, V.V., Mazepa, A.V., Brusilovskii, Y.E. et al. Reaction of 4,4-Dimethyl-1,3-dioxane with Dinitriles. Russian Journal of General Chemistry 71, 126–127 (2001). https://doi.org/10.1023/A:1012302127645

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1012302127645

Keywords

Navigation