Abstract
Neutral copper complexes of the deprotonated [(4-methylphenyl)sulfonyl]-1H-imino-(2-phenyl-2-oxazoline) proligands, [HTs-ROz], R = H, 5-Me, 4-Me, 4-Et, 4-iPr, have been prepared by electrochemical oxidation of anodic copper in an MeCN solution of the corresponding proligand. The [Cu(Ts-ROz)2] complexes were characterised by microanalysis, i.r. and electronic spectroscopies, and by e.p.r. and magnetic measurements. The crystal structures of HTs-5MeOz, [Cu(Ts-Oz)2], [Cu(Ts-5MeOz)2] and [Cu(Ts-4MeOz)2] were determined by X-ray diffraction.
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Cabaleiro, S., Pérez-Lourido, P., Castro, J. et al. Copper(II) [(4-methylphenyl)sulfonyl]-1H-imino-(2-phenyl-2-oxazoline) complexes. Transition Metal Chemistry 26, 709–716 (2001). https://doi.org/10.1023/A:1012078813896
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DOI: https://doi.org/10.1023/A:1012078813896