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Oxidative Transformations of Phenylacetylene on a Manganese(IV) Oxide Adsorbent-Catalyst

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Abstract

It is shown by IR spectroscopy and thermally programmed surface reactions that the complete oxidation of phenylacetylene on hydrated manganese dioxide in an adsorption catalytic regime occurs via dissociation of the C≡C bond (during chemisorption) with the formation of formate and benzoate on the surface.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauky Prospekt, 03039, Kyiv, Ukraine

    A. Yu. Kapran

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  1. A. Yu. Kapran
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Kapran, A.Y. Oxidative Transformations of Phenylacetylene on a Manganese(IV) Oxide Adsorbent-Catalyst. Theoretical and Experimental Chemistry 37, 189–191 (2001). https://doi.org/10.1023/A:1011936506495

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  • DOI: https://doi.org/10.1023/A:1011936506495

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