Skip to main content
Log in

Distribution of the Metals Lead, Cadmium, Copper, and Zinc in the Top Soil of Cartagena, Spain

  • Published:
Water, Air, and Soil Pollution Aims and scope Submit manuscript

Abstract

This article presents the results of the analysis of the metals lead, cadmium, copper, zinc and aluminum, conducted on a total of 112 soil samples arising from 57 sampling points, distributedthroughout the Cartagena area in southeastern Spain. Both, totalmetal content and soluble fraction (1 M nitric acid medium, exchangeable fraction) were analyzed. Soil samples were taken on the surface of the terrain and at a depth of 35 cm from eachsampling point. For the purposes of this study, sampling points were classified in three groups based on the results of previous research on air pollution in the region: clean areas,contaminated areas and vacant industrial areas. The statisticalanalyses of the results show no significant differences betweenthe surface samples and the 35 cm deep samples from all three areas. Lead, zinc and copper (soluble and total fractions) aresignificantly higher, and pH significantly lower, in the samples coming from the contaminated and vacant industrial areasthan in samples coming from the clean area. Total lead and cadmium are significantly higher in the vacant industrial areas(150 g kg-1 Pb and 9.3 g kg-1 Cd) than in the contaminated areas (5.2 g kg-1 Pb and 2.1 g kg-1 Cd).Iso-concentration maps have been prepared in order to correlatethe presence of metals with the industrial and mining activities in the region under study. These maps show a clear relationship between human activities and metal concentrationgradients, with peaks corresponding to both active and abandoned industrial and mining facilities.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Alloway, B. J.: 1995, ‘Soil Processes and the Behaviour of Heavy Metals’, in B. J. Alloway (ed.), Heavy Metals in Soils, Blackie Academic and Professional, London, U.K., pp. 11–37, 354.

    Google Scholar 

  • Baker, D. E. and Sneft, J. P.: 1995, ‘Copper’, in B. J. Alloway (ed.), Heavy Metals in Soils, Blackie Academic and Professional, London, U.K., pp. 179–205.

    Google Scholar 

  • Bermond, A. and Benzineb, K.: 1991, Water, Air, and Soil Pollut. 57–58, 883.

  • Bowen, J. M.: 1979, Environmental Chemistry of the Elements, Academic Press, London, 214 pp.

    Google Scholar 

  • Carter, M.: 1993, Soil Sampling and Methods of Analysis, Lewis Publishers, Boca Raton, FL, U.S.A., 814 pp.

    Google Scholar 

  • Cascales, J. A.: 1993, ‘Estudio de la Materia Particulada Sedimentable en Cartagena’, Ph.D. Thesis, Department of Chemical Engineering-Cartagena, University of Murcia, 274 pp.

  • El-Hassanín, A. S., Labib, T. M. and Dobal, A. T.: 1992, Water, Air, and Soil Pollut. 66, 239.

    Google Scholar 

  • Hopper, J. F., Ross, H. B., Sturges, W. T. and Barrie, L. A.: 1991, Tellus 43B, 45.

    Google Scholar 

  • Kiekens, L.: 1995, ‘Zinc’, in B. J. Alloway (ed.), Heavy Metals in Soils, Blackie Academic and Professional, London, U.K., pp. 284–303.

    Google Scholar 

  • Más, A. and Azcue, J. M.: 1993, Metales en Sistemas Biológicos, Promociones y Publicaciones Universitarias, Barcelona, 324 pp.

    Google Scholar 

  • Más Garcia, J.: 1986, Historia de Cartagena, Mediterráneo, Murcia, 412 pp.

    Google Scholar 

  • Mason, B.: 1966, Principles of Geochemistry, John Wiley & Sons, New York, 125 pp.

    Google Scholar 

  • Merrington, G and Alloway, B. J.: 1994, Water, Air, and Soil Pollut. 73, 333.

    Google Scholar 

  • Mortvedt, J. J., Giordano, P. M. and Lindsay, W. L.: 1983, ‘Micronutrientes en Agricultura’, AGT, México, 354 pp.

    Google Scholar 

  • Ostrander, R. and Clark, S. C.: 1991, ‘Soil Heavy Metal Concentrations and Erosion Damage in Upland Granlands in the Pennines, England’, Water, Air, and Soil Pollut. 59, 81.

    Google Scholar 

  • Pouyat, R. V. and McDonnell, M. J.: 1991, Water, Air, and Soil Pollut. 57–58, 797.

    Google Scholar 

  • Román, F.: 1987, ‘La Minería Española de Plomo y Cinc Frente a la CEE’, Industria Minera 267, 77–83.

    Google Scholar 

  • Seaker, E. M.: 1991, Water, Air, and Soil Pollut. 57–58, 849.

    Google Scholar 

  • Skoog, D. A. and West, D. M.: 1984, ‘Análisis Instrumental’, Nueva Editorial Interamericana, Mexico, 806 pp.

    Google Scholar 

  • Soon, Y. K. and Abboud, S.: 1993, ‘Cadmium, Chromium, Lead and Nickel’, in M. R. Carter (ed.), Soil Sampling and Methods of Analysis, Lewis Publishers, Boca Raton, FL, U.S.A., pp. 101–108.

    Google Scholar 

  • Villavecchia, V.: 1963, Tratado de Química Analítica Aplicada I, Gustavo Gili, Barcelona, 812 pp.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Martínez García, M.J., Moreno-Grau, S., Martínez García, J.J. et al. Distribution of the Metals Lead, Cadmium, Copper, and Zinc in the Top Soil of Cartagena, Spain. Water, Air, & Soil Pollution 131, 329–347 (2001). https://doi.org/10.1023/A:1011916218755

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1011916218755

Navigation