Abstract
A statistical quality control approachto detect changes in groundwater quality from aregulated waste unit is described. The approachapplies the combined Shewhart-CUSUM control chartmethodology for intrawell comparison of analyteconcentrations over time and does not require anupgradient well. A case study from the U.S.Department of Energy's Hanford Site is used forillustration purposes. This method is broadlyapplicable in groundwater monitoring programs wherethere is no clearly defined upgradient location, thegroundwater flow rate is exceptionally slow, or wherea high degree of spatial variability exists inparameter concentrations. This study also indicatesthat the use of the Data Quality Objectives (DQO)process can assist in designing an efficient andcost-effective groundwater monitoring plan to achievethe optimum goal of both low false positive and lowfalse negative rates (high power).
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Chou, C.J., O'Brien, R.F. & Brent Barnett, D. Application of Intrawell Testing of RCRA Groundwater Monitoring Data When No Upgradient Well Exists. Environ Monit Assess 71, 91–106 (2001). https://doi.org/10.1023/A:1011647913366
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DOI: https://doi.org/10.1023/A:1011647913366