Skip to main content
SpringerLink
Log in

Solid Solutions in The Cr2O3–α-Sb2O4–MoO3 System

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

DTA and XRD methods used to examine the Cr2O3–α-Sb2O4–MoO3 system have shown that a substitution solid solution of MoO3 in CrSbO4 is formed. A study of all the theoretically possible solid solution models has pointed to the fact that Mo6+ ions are incorporated into the CrSbO4 crystal lattice, in the place of Sb5+ ions and the compensation of redundant charges takes place through cation vacancies arising in an Sb5+ sub-lattice. The solubility limit for MoO3 in CrSbO4 does not exceed 25.00 mol%. CrSbO4(s.s.) is stable to ~1320°C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. M. Gaigneaux, M. J. Genet, P. Ruiz and B. Delmon, J. Phys. Chem. B, 104 (2000) 5724.

    Article  CAS  Google Scholar 

  2. J. B. Wang and M.-S. Chou, J. Air Waste Manage. Assoc., 50 (2000) 227.

    CAS  Google Scholar 

  3. D. W. Flick and M. C. Huff, Appl. Catal., A, 187 (1999) 13.

    Article  CAS  Google Scholar 

  4. J. Walczak, M. Kurzawa and E. Filipek, Thermochim. Acta, 150 (1989) 133.

    Article  CAS  Google Scholar 

  5. P. Tabero, React. Kinet. Catal. Lett., 67 (1999) 137.

    CAS  Google Scholar 

  6. E. Filipek, M. Kurzawa and G. Dąbrowska, J. Therm. Anal. Cal., 60 (2000) 167.

    Article  CAS  Google Scholar 

  7. K. Swaminathan and O. M. Sreedharan, J. Nucl. Mater., 275 (1999) 225.

    Article  CAS  Google Scholar 

  8. R. G. Teller, M. R. Antonio, J. F. Brazdil, M. Mehicic and R. K. Grasseli, Inorg. Chem., 24 (1985) 3370.

    Article  CAS  Google Scholar 

  9. E. Filipek, M. Kurzawa and G. Dąbrowska, 7th European Conference on Solid State Chemistry, Madrid 1999, Book of Abstracts, p. 55.

  10. Joint Committee of Powder Diffraction File: 6-0504, 11-694, 20-310, 35-609.

  11. J. Amador and J. Rasines, J. Appl. Cryst., 14 (1981) 348.

    Article  CAS  Google Scholar 

  12. R. D. Shannon, Acta Cryst., A32 (1976) 751.

    CAS  Google Scholar 

  13. C. A. Cody, L. DiCarlo and R. K. Darlington, Inorg. Chem., 18 (1979) 1572.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry and Environment Protection, Technical University of Szczecin, Al. Piastów 42, 71-065, Szczecin, Poland

    E. Filipek, M. Kurzawa & G. Dąbrowska

Authors
  1. E. Filipek
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Kurzawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. Dąbrowska
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Filipek, E., Kurzawa, M. & Dąbrowska, G. Solid Solutions in The Cr2O3–α-Sb2O4–MoO3 System. Journal of Thermal Analysis and Calorimetry 64, 1105–1111 (2001). https://doi.org/10.1023/A:1011572307844

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1011572307844

Search

Navigation