Skip to main content
SpringerLink
Log in

Heats of Mixing of Mixed Solvent Solutions of Alkali Metal Salts of Substituted Benzenesulfonic Acids

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The enthalpy change on mixing solutions of methyl-substituted benzenesulfonic acids and their salts, with salts having a common cation or anion, at constant ionic strength in mixtures of 1,4-dioxane with water, were measured at 25°C. The heat effects of mixing solutions having a common anion increase almost linearly with the reciprocal value of the dielectric constant of the solvent. The heat effects of mixing solutions having a common cation, which are all negative in water-rich solutions, become endothermic after a certain value of the dielectric constant is passed. The results are discussed in terms of the solute-solvent structural properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Dautzenberg, W. Jaeger, J. Kötz, B. Philipp, Ch. Seidel and D. Stscherbina, Polyelectrolytes, Carl Hanser Verlag, Munich 1994.

    Google Scholar 

  2. G. Vesnaver, M. Rudež, C. Pohar and J. Žkerjanc, J. Phys. Chem., 88 (1984) 2411.

    Article  CAS  Google Scholar 

  3. R. H. Wood and R. W. Smith, J. Phys. Chem., 69 (1965) 2974.

    Article  CAS  Google Scholar 

  4. R. A. Horne, Water and Aqueous Solutions, John Wiley & Sons, New York 1972, p. 628.

    Google Scholar 

  5. J. Škerjanc and M. Pavlin, J. Phys. Chem., 81 (1977) 1166.

    Article  Google Scholar 

  6. G. Vesnaver, M. Tatič and J. Škerjanc, J. Chem. Soc., Faraday Trans. I, 79 (1983) 699.

    Article  CAS  Google Scholar 

  7. C. Pohar and K. Arh, J. Solution Chem., 27 (1998) 1033.

    Article  CAS  Google Scholar 

  8. T. F. Young, Y. C. Wu and A. A. Krawetz, Discuss. Faraday Soc., 24 (1957) 37.

    Article  Google Scholar 

  9. R. M. Fuoss, A. Katchalsky and S. Lifson, Proc. Natl. Acad. Sci. U. S., 37 (1951) 578.

    Article  Google Scholar 

  10. G. E. Boyd, F. Vaslow and J. W. Chase, J. Chem. Phys., 71 (1967) 3879.

    Article  CAS  Google Scholar 

  11. K. Otrin Debevc, C. Pohar and V. Vlachy, J. Solution Chem., 25 (1996) 787.

    Article  Google Scholar 

  12. C. H. Patience, M. A. Kahlow, T. M. Bender and J. S. Johnson, Jr., J. Phys. Chem., 88 (1984) 4152.

    Article  Google Scholar 

  13. H. S. Frank and W. Y. Wen, Discuss. Faraday Soc., 24 (1957) 133.

    Article  Google Scholar 

  14. J. E. Desnoyers, M. Arel, G. Perron and C. Jolicoœur, J. Phys. Chem., 73 (1969) 3346.

    Article  CAS  Google Scholar 

  15. K. Otrin Debevc and C. Pohar, unpublished data.

  16. R. H. Wood and H. L. Anderson, J. Phys. Chem., 71 (1966) 1871.

    Article  Google Scholar 

  17. T. M. Fabry and R. M. Fuoss, J. Phys. Chem., 68 (1963) 971.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, 1000, Ljubljana, Slovenia

    C. Pohar, K. Arh & K. Škufca

Authors
  1. C. Pohar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Arh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Škufca
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pohar, C., Arh, K. & Škufca, K. Heats of Mixing of Mixed Solvent Solutions of Alkali Metal Salts of Substituted Benzenesulfonic Acids. Journal of Thermal Analysis and Calorimetry 64, 707–712 (2001). https://doi.org/10.1023/A:1011540310838

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1011540310838

Search

Navigation