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Thermal Behaviour of the N-donor Adducts of Metal Saccharinates: I. 2,2'-bipyridine saccharinato complexes of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II)

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Abstract

The adducts of Co, Ni, Cu, Zn and Pb saccharinates with 2,2'-bipyridine were synthesized and their thermal behaviour in the 20–1000°C temperature interval in a static air atmosphere was investigated. Regardless of the coordination, the decomposition starts with dehydration and proceeds with removal of the bipyridine ligand(s). The resulting metal(II) saccharinates adopt characteristic two-step decomposition, the first step being the SO2 release. Their stability was found tobe metal-dependent. The thermal decomposition pathways were correlated with the existing structural data about the compounds.

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Authors and Affiliations

  1. Institute of Chemistry, Faculty of Science, ‘Sv. Kiril i Metodij’ University, P.O. Box 162, MK-91001, Skopje, Macedonia

    P. Naumov, V. Jordanovska, O. Grupče & G. Jovanovski

  2. Faculty of Chemistry, Plovdiv University, Paisii Hilendarski, BG-4025 Plovdiv, Bulgaria

    B. Boyanov

Authors
  1. P. Naumov
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  2. V. Jordanovska
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  3. O. Grupče
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  4. B. Boyanov
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  5. G. Jovanovski
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Correspondence to P. Naumov.

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Naumov, P., Jordanovska, V., Grupče, O. et al. Thermal Behaviour of the N-donor Adducts of Metal Saccharinates: I. 2,2'-bipyridine saccharinato complexes of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II). Journal of Thermal Analysis and Calorimetry 65, 59–67 (2001). https://doi.org/10.1023/A:1011516316158

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  • DOI: https://doi.org/10.1023/A:1011516316158

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