Abstract
The solubility isotherm of the system La2O3—SeO2—H2O at 100°C was studied. The compounds of the three-component system were identified by the Schreinemakers method as well as by chemical and X-ray phase analyses. Simultaneous TG and DTA analyses of all compounds of the system were made by using a derivatograph. The mechanism of thermal decomposition was described.
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L. F. Nilson, Bull. Soc. Chem., 23 (1875) 262.
R. L. Espil, Compt. Rend., 152 (1911) 373.
Tr. Tomskovo Gos. University im. V. V. Kuibisheva, Seria Chimia, 154 (1962) 105.
E. Giesbrecht, M. Perier and W. W. Wendlandt, Ann. Acad. Brasileira de Ciencias, 34 (1962) 37.
L. Ya. Markovskii and R. A. Safina, J. Prik. Ch., 41 (1968) 693.
R. A. Safina, M. P. Morozova and L. Ya. Markovskii, Sbornik Chimia I. Tehnologia Luminoforov, Chimia, L., (1974) 93.
A. I. Maier, I. L. Suponickii and M. H. Karapetianz, Izv. AN SSSR, Neorgan materiali, 11 (1966) 775.
B. R. Morris, W. Harison and G. P. Stycky, Acta Cryst., 18 (1992) 1182.
M. de Pedro, I. Rasines and A. Castro, J. Mat. Sci. Letters, 12 (1993) 1637.
M. de Pedro, J. C. Trombe and A. Castro, J. Mat. Sci. Letters, 14 (1995) 994.
G. G. Gospodinov and M. G. Stancheva, J. Thermal Anal., 48 (1997) 1351.
V. Umland, A. Jansen, P. Tierg and C. Winsch, Teorie und Praktische Anwendung von Complexbildern, Dechema, Frankfurt am Main 1971.
I. I. Nasarenko and E. I. Ermakov, Analiticheskaia Khimiya Selena I Telura, Nauka, Moskow 1974, pp. 5, 59.
R. A. Safina, Aftoref. diss. kand. chem. nauk, L. GIPCH, 1969, p. 17.
L. Ya. Markovskii and R. A. Safina, Chimia I Tehnolgia Luminoforov, Khimiya, L., 1968, p. 109. (Tr. GIPCHJ, vip. 60).
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Gospodinov, G.G., Stancheva, M.G. Solubility Isotherm and Thermal Analysis of the Selenites of the Three-Component System La2O3—SeO2—H2O at 100°C. Journal of Thermal Analysis and Calorimetry 65, 275–280 (2001). https://doi.org/10.1023/A:1011509509314
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DOI: https://doi.org/10.1023/A:1011509509314