Abstract
The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group isP-1 with a = 11.6767(8) Å, b = 10.8680(8) Å and c = 11.4232(87rpar; Å α = 92.301(2)°, β = 106.932(2)° and γ = 103.2390(10)° V = 1341.02(16) Å3; Z = 2.
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John Plater, M., Foreman, M.R.S.J. & Skakle, J.M. Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer. Journal of Chemical Crystallography 30, 449–453 (2000). https://doi.org/10.1023/A:1011395315246
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DOI: https://doi.org/10.1023/A:1011395315246