Abstract
Oxidation of diterpene alkaloids by dimethyldioxirane was studied with eldeline, talatizamine, aconitine, and zongorine as examples. Nitrones and 19-oxo derivatives of bases were obtained. The results of the oxidation allow one to draw an analogy with the oxidation by KMnO4 and to suggest a mechanism of the reaction.
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Zinurova, E.G., Kabal"nova, N.N., Shereshovets, V.V. et al. Oxidation of diterpenoid alkaloids with dimethyldioxirane. Russian Chemical Bulletin 50, 720–723 (2001). https://doi.org/10.1023/A:1011385500970
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DOI: https://doi.org/10.1023/A:1011385500970