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Acidity of heteropoly acids with various structures and compositions studied by IR spectroscopy of the pyridinium salts

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Abstract

The acidity on the “proton affinity” scale was determined by IR spectroscopy of the pyridinium salts for nineteen heteropoly acids of nine structural types (including two with the previously unknown structure) and one isopoly acid. All heteropoly acids exhibited a high acidity at the level of CF3SO3H and HClO4. H3PW12O40 was the strongest acid.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Acad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    G. M. Maksimov, E. A. Paukshtis, A. A. Budneva, R. I. Maksimovskaya & V. A. Likholobov

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  1. G. M. Maksimov
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  2. E. A. Paukshtis
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  3. A. A. Budneva
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  4. R. I. Maksimovskaya
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  5. V. A. Likholobov
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Maksimov, G.M., Paukshtis, E.A., Budneva, A.A. et al. Acidity of heteropoly acids with various structures and compositions studied by IR spectroscopy of the pyridinium salts. Russian Chemical Bulletin 50, 587–590 (2001). https://doi.org/10.1023/A:1011384005996

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