Abstract
The crystal and molecular structure of the complex of Ni[(C2H5O)2PSNHNCPh(o-O)OMe]2 has been determined by X-ray crystallography. The compound crystallizes in the monoclinic system, space group P21/n, with lattice parameters a = 14.805(3), b = 7.9550(16), c = 15.176(3) Å, β = 117.94(3), and Z = 2. The unit cell contains two centrosymmetric molecules of O,O-diethylthiophosphorylhydrazine o-vanillin Schiff base nickel(II). The nickel(II) ion is coordinated in a slightly distorted trans square-planar configuration, the distortion consisting of a reduction of the N—Ni—O angle with the chelate rings from the ideal value of 90° to 87.69°. The coordination geometry of nickel(II) is square planar with two equivalent Ni—N and Ni—O bonds. The two phenyl rings and the phosphorylhydrazine moieties are in one plane forming an extensive delocalized system. Within each molecule, the two ligands are linked by a pair of N—H···O hydrogen bonding interactions. In the solid state, the title compound form a hydrogen bonding network through C—H···O intermolecular hydrogen bonding.
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Archer, C.M.; Dilworth, J.R.; Jobanputra, P.; Thomposon, R.M.; McPartlin, M.; Hiller, W. J. Chem. Soc. Dalton Trans. 1993, 897.
Shapiro, P.J.; Henling, L.M.; Marsh, R.E.; Bercaw, J.E. Inorg. Chem. 1990, 29, 4560.
Latham, J.A.; Leigh, G.J. J. Chem. Soc. Dalton Trans. 1986, 399.
Abrams, M.J.; Larsen, S.K.; Zubieta, J. Inorg. Chem. 1991, 30, 2031.
Wang, M.F.; Volkert, E.W.; Singh, P.R.; Katti, K.K.; Lusiak, P.; Katti, K.V.; Barnes, C.L. Inorg. Chem. 1994, 33, 1184.
Katti, K.V.; Singh, P.R.; Barnes, C.L. Inorg. Chem. 1992, 31, 4588.
Majoral, J.P.; Kraemer, R.; Navech, J.; Mathis, F. Polyhedron 1976, 32, 2633.
Koziara, A.; Turski, K. Sythesis 1986, 40, 298.
Bargrov, F.V.; Obshen, Zh. Khim. 1990, 60(5), 1028.
Booth, H.S. J. Am. Chem. Soc. 1948, 70, 2523.
Tolkmith, H. J. Am. Chem. Soc. 1962, 84, 2097.
SADABS. Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
Sheldrick, G.M. SHELXTL, v5 Reference Manual; Siemens Analytical X-ray Sysytems, Inc., Madison, WI, 1996.
Wilson, A.J.C. International Table for X-ray Crystallography, Volume C; Kluwer Academic Publishers, Dordrecht: The Netherlands, Tables 6.1.1.4 (pp 500-502) and 4.2.6.8 (pp 219–222), respectively, 1992.
Zhou, Z.Y.; Yu, K.B.; Gou, S.H.; You, X.Z.; Xu, Z. Polyhedron 1991, 1, 37-40.
Duan, C.Y.; You, X.Z.; Mak, T.C.W. Acta Crystallogr. 1998, C54, 31-33.
Tian, Y.P.; Duan, C.Y.; Lu, Z.L.; You, X.Z.; Fun, H.K.; Sivakumar, K. Acta Crystallogr. 1996, C52, 2150.
You, X.Z.; Xiong, R.G.; Dong, J.X.; Huang, X.Y. Polyhedron 1994, 19, 2763.
Huang, X.Y.; Xiong, R.G.; You, X.Z. Acta Crystallogr. 1995, C51, 2261.
Xiong, R.G.; You, X.Z.; Huang, X.Y. Acta Crystallogr. 1995, C51, 2263
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Xu, L., Ye, Q., Li, H. et al. Structure and characterization of O,O-diethylthiophosphorylhydrazine o-vanillin Schiff base nickel(II) complex: NiC24H36N4O8P2S2. Journal of Chemical Crystallography 30, 463–467 (2000). https://doi.org/10.1023/A:1011351500225
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DOI: https://doi.org/10.1023/A:1011351500225