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Reactions of (difluoroamino)trinitromethane with nucleophilic reagents

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Russian Chemical Bulletin Aims and scope

Abstract

Reactions of F2NC(NO2)3 with metal fluorides (KF and CsF) in DMF yield a substitution product of the fluorine atom for one nitro group, F2NC(NO2)2F. The reaction of F2NC(NO2)3 with LiBr in ethanol or DMF affords Br(NO2)C=NF rather than the expected bromo derivative F2NC(NO2)2Br.

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Authors and Affiliations

  1. State Research Institute “Kristall”, 6 ul. Zelenaya, 606007, Dzerzhinsk, Nizhnii Novgorod Region, Russian Federation

    G. Kh. Khisamutdinov

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119992, Moscow, Russian Federation

    S. A. Shevelev

Authors
  1. G. Kh. Khisamutdinov
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  2. S. A. Shevelev
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Khisamutdinov, G.K., Shevelev, S.A. Reactions of (difluoroamino)trinitromethane with nucleophilic reagents. Russian Chemical Bulletin 50, 736–737 (2001). https://doi.org/10.1023/A:1011345819626

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