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Chemiluminecsence in the oxidation of Na2C60 by the (NH4)2Ce(NO3)6 complex in THF

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Abstract

Chemiluminescence (λmax = 790 nm) in the oxidation of fulleride Na2C60 by the (NH4)2Ce(NO3)6 complex in THF was found. The 3C60* triplet of fullerene formed in the transfer of an electron from the intermediate C60 – anion to CeIV was suggested to be the chemiluminescence emitter.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Bashkortostan Republic Academy of Sciences and Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. G. Bulgakov, R. G. Akhmadieva, A. S. Musavirova & M. T. Golikova

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  1. R. G. Bulgakov
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  2. R. G. Akhmadieva
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  3. A. S. Musavirova
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  4. M. T. Golikova
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Bulgakov, R.G., Akhmadieva, R.G., Musavirova, A.S. et al. Chemiluminecsence in the oxidation of Na2C60 by the (NH4)2Ce(NO3)6 complex in THF. Russian Chemical Bulletin 50, 731–733 (2001). https://doi.org/10.1023/A:1011341718717

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