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Influence of Packing of Radical Cations on the Conductivity of the New Molecular Semiconductor (Doet)2ReO4

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Abstract

A new molecular semiconductor, (Doet)2ReO4(Doet is (1,4-dioxanediyl-2,3-dithio)ethylenedithiotetrathiafulvalene), is synthesized and examined by X-ray diffraction analysis. The crystal structure of (Doet)2ReO4is formed by [Doet]+1/2layers with isle [ReO4]–anions located between them. The Doet radical cations from the adjacent layers are linked by intermolecular hydrogen interactions of the O···H type.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Gritsenko, O. A. D'yachenko, A. I. Kotov & L. I. Buravov

  2. National Institute of Materials and Chemical Research, Tsukuba, Ibaraki, 305-8565, Japan

    M. Mizuno

Authors
  1. V. V. Gritsenko
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  2. O. A. D'yachenko
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  3. A. I. Kotov
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  4. L. I. Buravov
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  5. M. Mizuno
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Gritsenko, V.V., D'yachenko, O.A., Kotov, A.I. et al. Influence of Packing of Radical Cations on the Conductivity of the New Molecular Semiconductor (Doet)2ReO4. Russian Journal of Coordination Chemistry 27, 401–406 (2001). https://doi.org/10.1023/A:1011339825620

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  • DOI: https://doi.org/10.1023/A:1011339825620

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